Informativa e consenso per l'uso dei cookie

Accetto Il nostro sito salva piccoli pezzi di informazioni (cookie) sul dispositivo, al fine di fornire contenuti migliori e per scopi statistici. È possibile disattivare l'utilizzo di cookies modificando le impostazioni del tuo browser. Continuando la navigazione si acconsente all'utilizzo dei cookie.

7782-61-8 - Iron(III) nitrate nonahydrate, 98+% (metals basis) - 12226 - Alfa Aesar

12226 Iron(III) nitrate nonahydrate, 98+% (metals basis)

Codice CAS
7782-61-8
Sinonimi

Dimensioni Prezzo ($) Quantità Disponibilità
100g 18,54
1kg 43,67
5kg 82,71
Aggiungi al carrello Aggiungi al preventivo generale Visualizza articolo

Iron(III) nitrate nonahydrate, 98+% (metals basis)

MDL
MFCD00149708
EINECS
233-899-5

Proprietà chimiche

Formula
FeN3O9•9H2O
Peso formula
403.99 (241.86anhy)
Modulo
Crystalline, Contains excess HNO3
Punto di fusione
47°
Punto di ebollizione
125° dec.
Densità
1.684
Sensibilità
Moisture Sensitive
Solubilità
Soluble in water, alcohol and acetone.

Applicazioni

It is used as catalyst for the synthesis of sodium amide from sodium and ammonia, and for etching of silver and silver alloys. Ferric nitrate is used in the synthesis of organically templated iron phosphates, and acts as an efficient catalyst in enamination of beta dicarbonyl compounds to beta enaminones. Ferric nitrate impregnated clays are useful as oxidizing agents. Clayfen, produced from ferric nitrate and montmorillonite, is used for the oxidation of thiols to disulfide, and alcohols to aldehydes. Ferric nitrate is useful for regio- and stereo-selective nitration of various aromatic, aliphatic, and heteroaromatic olefins. This reaction provides nitroolefins with excellent E-selectivity. With Keggin-type heteropoly acids, it selectively oxidizes various hydroxy groups.

Note

Keep away from materials like organic and powdered metals.

Letteratura

Soni, P. A.; Gupta, P. K.; Maurya, C. K.; Halve, A. K.; Ganesan, K. Synthesis of 1,2-diones from 1,2-diols using iron(III) nitrate as oxidant under microwave irradiation. Tetrahedron Lett. 2015, 56 (21), 2817-2819.

Jastrzebski, R.; Van den Berg, E. J.; Weckhuysen, B. M.; Bruijnincx, P. C. A. Sustainable production of dimethyl adipate by non-heme iron(III) catalysed oxidative cleavage of catechol. Catal. Sci. Technol. 2015, 5, 2103-2109.

Rischio GHS e dichiarazioni precauzionali

Dichiarazioni di rischio (UE): H272-H315-H319

May intensify fire; oxidizer. Causes skin irritation. Causes serious eye irritation.

Dichiarazioni precauzionali: P221-P210-P220-P280-P305+P351+P338-P362-P321-P332+P313-P337+P313-P501a

Take any precaution to avoid mixing with combustibles. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep/Store away from clothing/combustible materials. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Take off contaminated clothing and wash before reuse. Specific treatment (see label). If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Dispose of contents/container in accordance with local/regional/national/international regulations.

Altri riferimenti

Merck
14,4027
Classe di rischio
5.1
Gruppo di imballaggio
III
Codice tariffe armonizzato
2834.29
TSCA
Yes
RTECS
NO7175000

Raccomandato

  • A15540

    Nickel(II) nitrate hexahydrate, 98%
  • A18521

    Manganese(II) nitrate tetrahydrate, 98%
  • 11341

    Cobalt(II) nitrate hexahydrate, 97.7% min
  • 11565

    Chromium(III) nitrate nonahydrate, 98.5%
  • 12357

    Iron(III) chloride, anhydrous, 98%

Visualizzati di recente

Prodotti chimici

Scienze della vita

Metalli e materiali

Catalizzatori

Apparecchiature di analisi e di laboratorio