Mercuric acetate is used as an oxidizing agent in organic synthesis. It is used in oxymercuration of double bonds. Mercuric acetate is used in non-aqueous titration. It is employed in the manufacture of phenyl mercury compounds which have pharmaceutical applications. It removes the acetamidomethyl protecting group from protected thiol, and converts thiocarbonate esters into dithiocarbonates. It promotes the addition of hydroxide and alkoxide across carbon-carbon double bonds.
Dethe, D. H.; Dherange, B. D.; Boda, R. Hg(OAc)2 mediated highly regio- and/or diastereoselective allylic tert-acetylation of olefins. Org. Chem. Front. 2015, 2, 159-162.
Chan, H. C.; Ko, T. P.; Huang, C. H.; Guo, R. T. Minireview: A Comeback of Hg-Derivatives in Protein Crystallography with Cys-Modification. ChemBioEng Rev. 2015, 2 (2), 133-140.
Dichiarazioni di rischio (UE): H300-H310-H330-H373
Fatal if swallowed. Fatal in contact with skin. Fatal if inhaled. May cause damage to organs through prolonged or repeated exposure.
Dichiarazioni precauzionali: P273-P280h-P309-P310a-P302+P352a-P501a
Avoid release to the environment. Wear protective gloves/clothing. IF exposed or if you feel unwell: IF ON SKIN: Dispose of contents/container in accordance with local/regional/national/international regulations.