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7705-08-0 - Iron(III) chloride, anhydrous, 98% - Ferric chloride - 12357 - Alfa Aesar

12357 Iron(III) chloride, anhydrous, 98%

Codice CAS
7705-08-0
Sinonimi
Ferric chloride

Dimensioni Prezzo ($) Quantità Disponibilità
10g 23,20
100g 29,10
1kg 34,80
5kg 56,80
25kg 226,00
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Iron(III) chloride, anhydrous, 98%

MDL
MFCD00011005
EINECS
231-729-4

Proprietà chimiche

Formula
Cl3Fe
Peso formula
162.21
Modulo
Crystalline
Punto di fusione
306°
Punto di ebollizione
316°
Densità
2.90
Sensibilità
Hygroscopic
Solubilità
Freely soluble in methanol, ethanol, ether, and acetone.

Applicazioni

It is used for sewerage treatment of industrial wastes, chloride hydrometallurgy (Silgarin process for the production of silicon), drinking water production, production of precursor for polyvinyl chloride (PVC), and copper-based metals in printed circuit boards. Iron (III) chloride is used as catalyst for the reaction of ethylene with chlorine, as a leaching agent, and as a drying reagent in certain reactions. It is a mild oxidizing agent and converts copper(I) chloride in to copper(II) chloride. As a moderately strong Lewis acid, it catalyzes chlorination of aromatic compounds and Friedel-Crafts reactions. Along with sodium iodide, it brings about reduction of organic azides to corresponding amines. It is useful in the detection of phenols and phenolic derivatives, gamma-hydroxybutyric acids, and also in Trinder spot test for detecting salicylic acids.

Note

Very sensitive to moisture and corrosive. Incompatible with strong oxidizing agents and forms explosive mixtures with sodium, and potassium.

Letteratura

Zhou, Y.; Xing, X. H.; Liu, Z.; Cui, L.; Yu, A.; Feng, Q.; Yang, H. Enhanced coagulation of ferric chloride aided by tannic acid for phosphorus removal from wastewater. Chemosphere 2008, 72 (2), 290-298.

Sarhan, A. A. O.; Bolm, C. Iron(III) chloride in oxidative C-C coupling reactions. Chem. Soc. Rev. 2009, 38, 2730-2744.

Rischio GHS e dichiarazioni precauzionali

Dichiarazioni di rischio (UE): H314-H318-H302

Causes severe skin burns and eye damage. Causes serious eye damage. Harmful if swallowed.

Dichiarazioni precauzionali: P280-P305+P351+P338-P309-P310

Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF exposed or if you feel unwell: Immediately call a POISON CENTER or doctor/physician.

Altri riferimenti

Merck
14,4019
Classe di rischio
8
Gruppo di imballaggio
III
Codice tariffe armonizzato
2827.39
TSCA
Yes
RTECS
LJ9100000

Raccomandato

  • B22031

    Cobalt(II) chloride, anhydrous, 97%
  • 11868

    Manganese(II) chloride, 97%
  • 12226

    Iron(III) nitrate nonahydrate, 98+% (metals basis)
  • 12457

    Copper(II) chloride, anhydrous, 98% min
  • 31141

    Iron(II) chloride, anhydrous, 99.5% (metals basis)

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