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10025-77-1 - Iron(III) chloride hexahydrate, ACS, 97.0-102.0% - Ferric chloride hexahydrate - 12497 - Alfa Aesar

12497 Iron(III) chloride hexahydrate, ACS, 97.0-102.0%

Codice CAS
10025-77-1
Sinonimi
Ferric chloride hexahydrate

Dimensioni Prezzo ($) Quantità Disponibilità
25g 19,20
250g 33,40
1kg 97,10
5kg 335,00
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Iron(III) chloride hexahydrate, ACS, 97.0-102.0%

MDL
MFCD00149712
EINECS
231-729-4

Proprietà chimiche

Formula
Cl3Fe•6H2O
Peso formula
270.30 (162.21anhy)
Modulo
Lump
Punto di fusione
37°
Punto di ebollizione
280-285°
Densità
1.820
Sensibilità
Hygroscopic
Solubilità
Freely soluble in water, alcohol, ether, acetone.Soluble in water, alcohol, glycerol, methanol, ether and acetone. Insoluble in ethyl acetate.

Specifiche categoria

Maximum level of impurities: Insoluble matter 0.01%, NO<sub>3</sub> 0.01%, Phosphorus compounds (as PO<sub>4</sub>) 0.01%, SO<sub>4</sub> 0.01%, Ca 0.01%, Cu 0.003%, Mg 0.005%, K 0.005%, Na 0.05%, Ferrous iron (Fe<sup>+</sup>lambda) P.T. (limit about 0.002%), Zn 0.003%

Applicazioni

Iron(III) chloride hexahydrate is used to prepare organically templated iron phosphates. It is used for sewerage treatment of industrial wastes, chloride hydrometallurgy (Silgarin process for the production of silicon), drinking water production, production of precursors for polyvinyl chloride (PVC) and copper-based metals in printed circuit boards. It plays an important role in photoengraving and photography as an etching agent. It is useful as a mordant in dyeing and printing textiles. It is useful in the detection of phenols and phenolic derivatives; gamma-hydroxybutyric acids and also in the Trinder spot test for detecting salicylic acids.

Note

b.p. 280° -H{2}O; 300° dec.Hygroscopic. Keep the container tightly closed in a dry and well-ventilated place. Incompatible with strong oxidizing agents, sodium and sodium oxides and potassium.

Letteratura

Wang, L.; Li, J.; Lv, Y.; Zhao, G.; Gao, S. Selective aerobic oxidation of alcohols catalyzed by iron chloride hexahydrate/TEMPO in the presence of silica gel. Appl. Organomet. Chem. 2012, 26 (1), 37-43.

Desogus, P.; Manca, P. P.; Orru, G.; Zucca, A. Stabilization-solidification treatment of mine tailings using Portland cement, potassium dihydrogen phosphate and ferric chloride hexahydrate. Miner. Eng. 2013, 45, 47-54.

Rischio GHS e dichiarazioni precauzionali

Dichiarazioni di rischio (UE): H314-H318-H302

Causes severe skin burns and eye damage. Causes serious eye damage. Harmful if swallowed.

Dichiarazioni precauzionali: P280-P305+P351+P338-P309-P310

Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF exposed or if you feel unwell: Immediately call a POISON CENTER or doctor/physician.

Altri riferimenti

Merck
14,4019
Classe di rischio
8
Gruppo di imballaggio
III
Codice tariffe armonizzato
2827.39
TSCA
Yes
RTECS
NO5425000

Raccomandato

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    Silver nitrate, ACS, 99.9+% (metals basis)
  • 12484

    Iron(II) chloride hydrate, Reagent Grade, 99%
  • 33399

    Zinc sulfate heptahydrate, ACS, 99.0-103.0%
  • 36554

    Cobalt(II) chloride hexahydrate, ACS, 98.0-102.0%

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