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1333-82-0 - Chromium(VI) oxide, 99% - 12522 - Alfa Aesar

12522 Chromium(VI) oxide, 99%

Codice CAS
1333-82-0
Sinonimi

Dimensioni Prezzo ($) Quantità Disponibilità
250g 26,47
1kg 52,58
*5x1kg 183,20
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Chromium(VI) oxide, 99%

MDL
MFCD00010952
EINECS
215-607-8

Proprietà chimiche

Formula
CrO3
Peso formula
99.99
Modulo
Crystalline
Punto di fusione
196°
Punto di ebollizione
250° dec.
Densità
2.7
Sensibilità
Hygroscopic
Solubilità
Very soluble in water. Soluble in sulfuric, nitric acid, acetic acid, and acetone.

Applicazioni

It is widely used in chromium electroplating, and as protective coatings in corrosion/oxidation resistance of metals. It is also employed in CDs and DVDs. It is useful as an oxidant in Jones oxidation in acetic acid or acetone. It is used in the oxidation of primary alcohols into carboxylic acids, and secondary alcohols into ketones. With phosphoric acid, it is used as a stripping agent for anodic coatings of all types and in the production of syntheric rubies.

Note

It is a non-flammable stable compound. When heated above 197 °C, it liberates oxygen, producing chromium(III) oxide.

Letteratura

Calabrese, D. R.; Wenning, B.; Finlay, J. A.; Callow, M. E.; Callow, J. A.; Fischer, D.; Ober, K. C. Amphiphilic oligopeptides grafted to PDMS-based diblock copolymers for use in antifouling and fouling release coatings. Polym. Advan. Technol. 2015, 26 (7), 829-836.

Wang, C.; Hu, H.; Xu, J.; Kan, W. One-pot synthesis of indolizine via 1,3-dipolar cycloaddition using a sub-equivalent amount of K2Cr2O7 as an efficient oxidant under base free conditions. RSC Adv. 2015, 5, 41255-41258.

Rischio GHS e dichiarazioni precauzionali

Dichiarazioni di rischio (UE): H271-H301-H310-H330-H317-H334-H340-H350-H372-H361-H314-H318-H400-H410

May cause fire or explosion; strong oxidizer. Toxic if swallowed. Fatal in contact with skin. Fatal if inhaled. May cause an allergic skin reaction. May cause allergy or asthma symptoms or breathing difficulties if inhaled. May cause genetic defects. May cause cancer. Causes damage to organs through prolonged or repeated exposure. Suspected of damaging fertility or the unborn child. Causes severe skin burns and eye damage. Causes serious eye damage. Very toxic to aquatic life. Very toxic to aquatic life with long lasting effects.

Dichiarazioni precauzionali: P221-P283-P301+P310-P303+P361+P353-P304+P340-P305+P351+P338-P320-P330-P361-P405-P501a

Take any precaution to avoid mixing with combustibles. Wear fire/flame resistant/retardant clothing. IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Specific treatment is urgent (see label). Rinse mouth. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Altri riferimenti

Merck
14,2235
Classe di rischio
5.1
Gruppo di imballaggio
II
Codice tariffe armonizzato
2819.10
TSCA
Yes
RTECS
GB6650000

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