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7647-10-1 - Palladium(II) chloride, solution, Pd 9.0-11.0% w/w (cont. Pd) - 12623 - Alfa Aesar

12623 Palladium(II) chloride, solution, Pd 9.0-11.0% w/w (cont. Pd)

Codice CAS
7647-10-1
Sinonimi

Dimensioni Prezzo ($) Quantità Disponibilità
(c)1g 141,00
(c)5g 500,00
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Palladium(II) chloride, solution, Pd 9.0-11.0% w/w (cont. Pd)

MDL
MFCD00003558
EINECS
231-596-2

Proprietà chimiche

Formula
PdCl2
Peso formula
177.31
Modulo
Liquid
Solubilità
Miscible with water, organic solvents and hydrochloric acid.

Applicazioni

Palladium(II) chloride is used to remove the stain present stainless steel . Its solutions are used to test the corrosion-resistance of stainless steel. It is used in carbon monoxide detectors. It is also used for cosmetic tatooing of leukomas in thecornea and in the preparation of palladium(II) iodide by reacting with potassium iodide. It is involved in the synthesis of semiconducting metal-containing polymers. It is used as a catalyst for carbonylation of organic tellurides and deamination of phenethylamines to phenyl substituted pyrroles with copper(I) as co catalyst. It plays an important role in the hydrodimerization of butadiene to form octa-2,7-dien-1-ol.

Note

Incompatible with organic solvents, acids, ammonia, zinc, strong oxidizing agents, aluminum, magnesium, nitrates and thiocyanates.

Letteratura

Yamaguchi, T.; Yamaguchi, E.; Tada, N.; Itoh, A. Direct ortho-Hydroxylation of 2-Phenylpyridines using Palladium(II) Chloride and Hydrogen Peroxide. Adv. Synth. Catal. 2015, 357 (9), 2017-2021.

Banti, C. N.; Charalampou, D. C.; Kourkoumelis, N.; Owczarzak, A. M.; Kubicki, M.; Hadjikakou, S. K.; Hadjiliadis, N. Mono-nuclear cis-Pd(II) chloride complex of the thio-nucleotide analogue 5-methyl-thiouracil and its biological activity. Polyhedron 2015, 87, 251-258.

Rischio GHS e dichiarazioni precauzionali

Dichiarazioni di rischio (UE): H290-H302-H314-H318-H317

May be corrosive to metals. Harmful if swallowed. Causes severe skin burns and eye damage. Causes serious eye damage. May cause an allergic skin reaction.

Dichiarazioni precauzionali: P260u-P303+P361+P353-P305+P351+P338-P301+P330+P331-P405-P501a

IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Altri riferimenti

Classe di rischio
8
Gruppo di imballaggio
II
Codice tariffe armonizzato
2843.90
TSCA
Yes

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