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Chloro(1,5-cyclooctadiene)iridium(I) dimer is widely used as a precursor to other iridium complexes, which finds application in homogeneous catalysis like carbonylation, hydrosilylation, hydrofomylation, asymmetric allylic substitutions, metathesis and chiral catalysis reactions. It is involved in the preparation of Crabtree's catalyst, which is used for hydrogenation and hydrogen-transfer reactions.
John, J.; Wilson-Konderka, C.; Metallinos, C. Low Pressure Asymmetric Hydrogenation of Quinolines using an Annulated Planar Chiral N-Ferrocenyl NHC-Iridium Complex. Adv. Synth. Catal. 2015, 357 (9), 2071-2081.
El Amouri, H.; Gruselle, M.; Jaouén, G. bis[Dichloro(η-pentamethylcyclopentadienyl)rhodium(III) and-iridium(III)] from bis[Chloro(1, 5-cyclooctadiene)rhodium(I) and-iridium(I)] Oxidation, and Formation of 1, 5-Cyclooctadiene(η-pentamethylcyclopentadienyl)rhodium(I). Synth. React. Inorg. Met.-Org. Chem. 2015, 24 (3), 395-400.
Dichiarazioni di rischio (UE): H315-H319-H335
Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.
Dichiarazioni precauzionali: P261-P280a-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves and eye/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.