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534-17-8 - Cesium carbonate, 99% (metals basis) - 12887 - Alfa Aesar

12887 Cesium carbonate, 99% (metals basis)

Codice CAS
534-17-8
Sinonimi

Dimensioni Prezzo ($) Quantità Disponibilità
5g 14,20
50g 43,20
250g 143,00
1kg 454,00
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Cesium carbonate, 99% (metals basis)

MDL
MFCD00010957
EINECS
208-591-9

Proprietà chimiche

Formula
Cs2CO3
Peso formula
325.82
Modulo
Powder/Granules
Punto di fusione
610° dec.
Densità
4.072
Sensibilità
Hygroscopic
Solubilità
Freely soluble in water. Soluble in ethanol, dimethylformamide and dimethyl sulfoxide.

Applicazioni

Cesium carbonate is the precursor for other cesium compounds. It acts as a base in sensitive organic reactions. Suzuki, Heck and Sonogashira synthesis are some of the important reactions involving cesium carbonate. It finds use in solar cells as it increases the power conversion efficiency of cells through the transfer of electrons. It is also used in the production of special optical glasses, petroleum catalytic additives, special ceramics, and in sulfuric acid industry. It is useful in the N-alkylation (of sulfonamides, beta-lactams, indoles, heterocycles, and several sensitive nitrogen compounds), carbamination of amines, carbonylation of alcohols, and aerobic oxidation of alcohols into carbonyl compounds without over oxidations.

Note

Hygroscopic. It is incompatible with strong oxidizing agents, metals and acids.

Letteratura

Fu, R.; Forsythe, E.; Shi, J.; Srour, M.; Blomquist, S.; Morton, D. Temperature dependence of cesium carbonate-doped electron transporting layers on organic light-emitting diodes. Synth. Met. 2015, 209, 128-134.

Chen, Y. C.; Gao, C. Y.; Chen, K. L.; Sze, P. W.; Huang, C. J. Enhanced electronic injection in organic light-emitting diodes by incorporating silver nanoclusters and cesium carbonate. Appl. Surf. Sci. 2015, 351, 232-235.

Rischio GHS e dichiarazioni precauzionali

Dichiarazioni di rischio (UE): H315-H319-H335-H303

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation. May be harmful if swallowed.

Dichiarazioni precauzionali: P261-P280-P305+P351+P338-P304+P340-P362-P312-P321-P405-P403+P233-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. Call a POISON CENTER or doctor/physician if you feel unwell. Specific treatment (see label). Store locked up. Store in a well-ventilated place. Keep container tightly closed. Dispose of contents/container in accordance with local/regional/national/international regulations.

Altri riferimenti

Merck
14,2010
Beilstein
4546405
Codice tariffe armonizzato
2836.99
TSCA
Yes
RTECS
FK9400000

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