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95838-16-7 - Cerium(IV) sulfate hydrate, 98% - Ceric sulfate hydrate - A10142 - Alfa Aesar

A10142 Cerium(IV) sulfate hydrate, 98%

Codice CAS
95838-16-7
Sinonimi
Ceric sulfate hydrate

Cerium(IV) sulfate hydrate, 98%

MDL
MFCD00149427
EINECS
237-029-5

Proprietà chimiche

Formula
Ce(SO4)2•xH2O
Peso formula
332.24(anhy)
Punto di fusione
195° dec.
Densità
3.01
Solubilità
Soluble in water.

Applicazioni

Cerium(IV) sulfate hydrate is used as a general application for chemical intermediate.

Note

Store in cool, dry conditions in well sealed containers. keep container tightly closed

Letteratura

M. P. Singh; H. S. Singh; M. K. Verma. Kinetics and mechanism of the ruthenium(III) chloride catalyzed oxidation of butanone-2 and pentanone-3 by cerium(IV) sulfate in aqueous sulfuric acid medium. J. Phys. Chem. 1980, 84,(3), 256-259.

Oxidizing agent which has been used for the generation of o-benzoquinone from catechol: Liebigs Ann. Chem., 712, 214 (1968).

Promotes the formation of radicals from dialkyl malonates, which undergo substitution reactions with furans and thiophenes: Heterocycles, 27, 2627 (1988).

In the presence of oxygen, oximes can be converted to the parent carbonyl compounds in good yield: Appl. Organomet. Chem., 13, 867 (1999).

In combination with iodine in EtOH, 2-alkylcycloalkanones are ring-opened to ethyl keto esters: J. Chem. Res. (Synop.), 122 (1999).

Rischio GHS e dichiarazioni precauzionali

Dichiarazioni di rischio (UE): H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Dichiarazioni precauzionali: P261-P280a-P305+P351+P338-P304+P340-P405-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves and eye/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Altri riferimenti

Merck
14,1990
Codice tariffe armonizzato
2846.10
TSCA
Yes
RTECS
WS6960000

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