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707-07-3 - Trimethyl orthobenzoate, 98% - Orthobenzoic acid trimethyl ester - alpha,alpha,alpha-Trimethoxytoluene - A10270 - Alfa Aesar

A10270 Trimethyl orthobenzoate, 98%

Codice CAS
707-07-3
Sinonimi
Orthobenzoic acid trimethyl ester
alpha,alpha,alpha-Trimethoxytoluene

Dimensioni Prezzo ($) Quantità Disponibilità
10g 32,90
50g 125,00
250g 521,00
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Trimethyl orthobenzoate, 98%

MDL
MFCD00008474
EINECS
211-897-5

Proprietà chimiche

Formula
(C6H5)C(OCH3)3
Peso formula
182.22
Punto di ebollizione
87-88°/7mm
Punto di infiammabilità
82°(179°F)
Densità
1.060
Indice di rifrazione
1.4890
Sensibilità
Moisture Sensitive
Solubilità
Soluble in organic solvents.

Applicazioni

Trimethyl orthobenzoate was used in the preparation of 5-phenyl-4,6-dipyrrin and 2,3-orthoester derivatives of ethyl-1-thio-α-L-rhamnopyranoside. It reacts with indole to prepare indol-3-yl-phenyl-methanone.

Note

Moisture Sensitive. Protect from humidity and water. Store under dry inert gas. Incompatible with oxidizing agents and moisture.

Letteratura

R G Hicks; L Ohrström; G W Patenaude. Spin distributions, ring conformations, and spiroconjugation in "phosphaverdazyl" radicals. Inorganic Chemistry. 2001, 40 (8), 1865-1870.

Reaction with BF3 etherate gives the selective alkylating agent, phenyldimethoxycarbenium tetrafluoroborate, stable for a few weeks at 0o: Synth. Commun., 19, 2307 (1989).

Rischio GHS e dichiarazioni precauzionali

Dichiarazioni di rischio (UE): H315-H319-H335-H227

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation. Combustible liquid.

Dichiarazioni precauzionali: P210-P261-P280-P305+P351+P338-P304+P340-P362-P312-P405-P403+P233-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. Call a POISON CENTER or doctor/physician if you feel unwell. Store locked up. Store in a well-ventilated place. Keep container tightly closed. Dispose of contents/container in accordance with local/regional/national/international regulations.

Altri riferimenti

Beilstein
777623
Codice tariffe armonizzato
2916.39
TSCA
Yes

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