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485-47-2 - Ninhydrin, 99% - 2,2-Dihydroxy-1,3-indanedione - 1,2,3-Indantrione - A10409 - Alfa Aesar

A10409 Ninhydrin, 99%

Codice CAS
485-47-2
Sinonimi
2,2-Dihydroxy-1,3-indanedione
1,2,3-Indantrione

Dimensioni Prezzo ($) Quantità Disponibilità
10g 16,72
25g 35,43
50g 62,62
250g 267,80
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Ninhydrin, 99%

MDL
MFCD00003791
EINECS
207-618-1

Proprietà chimiche

Formula
C9H6O4
Peso formula
178.14
Punto di fusione
251° dec.
Sensibilità
Light Sensitive
Solubilità
Soluble in water, acetone, ethanol, and methanol. Slightly soluble in chloroform and ether.

Applicazioni

Ninhydrin is used for the determination of amino groups in amino acids, peptides and proteins. It finds application in forensic science for the analysis of latent fingerprints on porous surfaces such as paper. It is also used in thin layer chromatography (TLC) to monitor the progress of chemical reactions. In Kaiser test, it plays an important role to monitor the deprotection in solid phase peptide synthesis.

Note

Light Sensitive. Incompatible with strong oxidizing agents, amines, alkalis and strong bases.

Letteratura

Reagent for the detection and determination of peptides and amino acids.

Reviews: Chem. Rev., 60, 39 (1960); Tetrahedron, 34, 1285 (1978); 47, 8791 (1991).

Babu, K. R.; Khan, F. A. A domino reaction of tetrahalo-7, 7-dimethoxybicyclo [2.2. 1] heptenyl alcohols leading to indenones and a de novo synthesis of ninhydrin derivatives. Org. Biomol. Chem. 2015, 13 (1), 299-308.

Omar, M. A.; Hammad, M. A.; Nagy, D. M.; Aly, A. A. Development of spectrofluorimetric method for determination of certain aminoglycoside drugs in dosage forms and human plasma through condensation with ninhydrin and phenyl acetaldehyde. Spectrochim. Acta, Part A 2015, 136, 1760-1766.

Rischio GHS e dichiarazioni precauzionali

Dichiarazioni di rischio (UE): H302-H315-H319-H335

Harmful if swallowed. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Dichiarazioni precauzionali: P261-P280-P305+P351+P338-P304+P340-P362-P301+P312-P312-P405-P403+P233-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. Store locked up. Store in a well-ventilated place. Keep container tightly closed. Dispose of contents/container in accordance with local/regional/national/international regulations.

Altri riferimenti

Merck
14,6554
Beilstein
1910963
Codice tariffe armonizzato
2914.39
TSCA
Yes
RTECS
NK5425000

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