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536-90-3 - m-Anisidine, 98% - 3-Aminoanisole - 3-Methoxyaniline - A10815 - Alfa Aesar

A10815 m-Anisidine, 98%

Codice CAS
536-90-3
Sinonimi
3-Aminoanisole
3-Methoxyaniline

Dimensioni Prezzo ($) Quantità Disponibilità
50g 30,68
250g 102,60
1000g 259,20
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m-Anisidine, 98%

MDL
MFCD00007783
EINECS
208-651-4

Proprietà chimiche

Formula
C7H9NO
Peso formula
123.16
Punto di fusione
-1°
Punto di ebollizione
250-251°
Punto di infiammabilità
126°(258°F)
Densità
1.101
Indice di rifrazione
1.5810
Sensibilità
Light Sensitive
Solubilità
Soluble in water(18g/L).

Applicazioni

The unusually large amount of dibromo product produced upon bromination of m-anisidine may be attributed to the two doubly activeated positions. The best enantioselectivity of 97 % ee was observed for the reaction of m-anisidine in organocatalytic asymmetric three-component cyclization of cinnamaldehydes and primary amines with 1, 3-Dicarbonyl Compounds. Evidence for the control of 2nd-harmonic generation activities from the x-ray crystal-structures of the complexes of l-tartaric acid with m-anisidine and p-toluidine was determined.

Note

Light Sensitive. Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents.

Letteratura

W. Preston Reeves,; Rufus M. King . A Convenient Method for Bromination of Aromatic Amines. Synthetic Communications: An International Journal for Rapid Communication of Synthetic Organic Chemistry . 1993, 23 (6), 855-859.

Renuka K,; RowTNG,; Prasad BR,; Subramanian CK,;Bhattacharya, S .Hydrogen-Bond-Directed Nonlinear-Optical Organic Materials - Evidence For The Control Of 2nd-Harmonic Generation Activities From The X-Ray Crystal-Structures Of The Complexes Of L-Tartaric Acid With M-Anisidine and P-Toluidine . Hydrogen-Bond-Directed Nonlinear-Optical Organic Materials. 1995, 19 (1), 83-89..

Rischio GHS e dichiarazioni precauzionali

Dichiarazioni di rischio (UE): H400-H410-H302-H315-H319-H335

Very toxic to aquatic life. Very toxic to aquatic life with long lasting effects. Harmful if swallowed. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Dichiarazioni precauzionali: P261-P273-P280-P305+P351+P338-P304+P340-P362-P301+P312-P312-P405-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Avoid release to the environment. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Altri riferimenti

Merck
14,667
Beilstein
386119
Classe di rischio
6.1
Gruppo di imballaggio
III
Codice tariffe armonizzato
2922.29
TSCA
Yes
RTECS
BZ5408000

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