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536-90-3 - m-Anisidine, 98% - 3-Aminoanisole - 3-Methoxyaniline - A10815 - Alfa Aesar

A10815 m-Anisidine, 98%

Codice CAS
536-90-3
Sinonimi
3-Aminoanisole
3-Methoxyaniline

Dimensioni Prezzo ($) Quantità Disponibilità
50g 34,00
250g 105,00
1000g 318,00
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m-Anisidine, 98%

MDL
MFCD00007783
EINECS
208-651-4

Proprietà chimiche

Formula
C7H9NO
Peso formula
123.16
Punto di fusione
-1°
Punto di ebollizione
250-251°
Punto di infiammabilità
126°(258°F)
Densità
1.101
Indice di rifrazione
1.5810
Sensibilità
Light Sensitive
Solubilità
Soluble in water(18g/L).

Applicazioni

The unusually large amount of dibromo product produced upon bromination of m-anisidine may be attributed to the two doubly activeated positions. The best enantioselectivity of 97 % ee was observed for the reaction of m-anisidine in organocatalytic asymmetric three-component cyclization of cinnamaldehydes and primary amines with 1, 3-Dicarbonyl Compounds. Evidence for the control of 2nd-harmonic generation activities from the x-ray crystal-structures of the complexes of l-tartaric acid with m-anisidine and p-toluidine was determined.

Note

Light Sensitive. Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents.

Letteratura

W. Preston Reeves,; Rufus M. King . A Convenient Method for Bromination of Aromatic Amines. Synthetic Communications: An International Journal for Rapid Communication of Synthetic Organic Chemistry . 1993, 23 (6), 855-859.

Renuka K,; RowTNG,; Prasad BR,; Subramanian CK,;Bhattacharya, S .Hydrogen-Bond-Directed Nonlinear-Optical Organic Materials - Evidence For The Control Of 2nd-Harmonic Generation Activities From The X-Ray Crystal-Structures Of The Complexes Of L-Tartaric Acid With M-Anisidine and P-Toluidine . Hydrogen-Bond-Directed Nonlinear-Optical Organic Materials. 1995, 19 (1), 83-89..

Rischio GHS e dichiarazioni precauzionali

Dichiarazioni di rischio (UE): H302-H315-H319-H335

Harmful if swallowed. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Dichiarazioni precauzionali: P261-P280a-P305+P351+P338-P304+P340-P405-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves and eye/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Altri riferimenti

Merck
14,667
Beilstein
386119
Classe di rischio
6.1
Gruppo di imballaggio
III
Codice tariffe armonizzato
2922.29
TSCA
Yes
RTECS
BZ5408000

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