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2-Picoline is used as an intermediate in agrochemicals and pharmaceuticals. It serves as a solvent as well as to prepare dyes and resins. It finds application as a constituent in cigarette smoke, bone oil, coal tar and coke oven emissions. Further, it acts as a precursor of 2-vinylpyridine, picolinic acid and nitrapyrin. It is also employed to study the electron and proton transfer reactions of lumiflavin. In addition, it is used in the synthetic pathway for the preparation of dearomatized, allylated and carbon-hydrogen bond activated pyridine derivatives.
Dhau, J. S.; Singh, A. A study on the BF3-directed lithiation of 2-picoline and 2,3-lutidine. J. Organomet. Chem. 2014, 749, 109-114.
Li, B.; Wei, H.; Li, H.; Pereshivko, O. P.; Peshkov, V. A. Direct addition of 2-methylazines to aryl glyoxals for the synthesis of alpha-hydroxy ketones. Tetrahedron Lett. 2015, 56 (37), 5231-5234.
Dichiarazioni di rischio (UE): H226-H302-H312-H332-H319-H335
Flammable liquid and vapour. Harmful if swallowed. Harmful in contact with skin. Harmful if inhaled. Causes serious eye irritation. May cause respiratory irritation.
Dichiarazioni precauzionali: P210-P261-P303+P361+P353-P305+P351+P338-P405-P501a
Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Avoid breathing dust/fume/gas/mist/vapours/spray. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.