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328-73-4 - 1-Iodo-3,5-bis(trifluoromethyl)benzene, 97+% - 3,5-Bis(trifluoromethyl)iodobenzene - A10878 - Alfa Aesar

A10878 1-Iodo-3,5-bis(trifluoromethyl)benzene, 97+%

Codice CAS
328-73-4
Sinonimi
3,5-Bis(trifluoromethyl)iodobenzene

Dimensioni Prezzo ($) Quantità Disponibilità
5g 49,02
25g 196,00
100g 663,20
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1-Iodo-3,5-bis(trifluoromethyl)benzene, 97+%

MDL
MFCD00040837

Proprietà chimiche

Formula
C8H3F6I
Peso formula
340.01
Punto di ebollizione
62-64°/12mm
Punto di infiammabilità
74°(165°F)
Densità
1.919
Indice di rifrazione
1.4645
Sensibilità
Light Sensitive
Solubilità
Slightly soluble in water.

Applicazioni

3,5-bis(trifluoromethyl)pheny1- magnesium iodide was prepared from 1-iodo-3,5- bis(trifluoromethyl)benzene. Monodeprotected masked hexayne was not particularly stable and hence was used directly without purification in a Sonogashira coupling with 1-iodo-3,5-bis(trifluoromethyl)benzene to provide mono-aryl-end-capped masked hexayne.

Note

Light Sensitive. Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents, light.

Letteratura

Hiroshi Nishida,; Naoko Takada,; Masaji Yoshimura,; Takaaki Sonoda,; Hiroshi Kobayashi. Tetrakis[3,5-bis(trifluoromethyl)phenyl]borate. Highly Lipophilic Stable Anionic Agent for Solvent-extraction of Cations . Bulletin of the Chemical Society of Japane. 1984, 57 (9), pg no.

Simon M. E. Simpkins,; Michael D. Weller,; Liam R. Cox. β-Chlorovinylsilanes as masked alkynes in oligoyne assembly: synthesis of the first aryl-end-capped dodecayne. Chem. Commun. 2007, 39, 4035-4037.

Rischio GHS e dichiarazioni precauzionali

Dichiarazioni di rischio (UE): H315-H319-H335-H227

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation. Combustible liquid.

Dichiarazioni precauzionali: P210-P261-P280-P305+P351+P338-P304+P340-P362-P312-P405-P403+P233-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. Call a POISON CENTER or doctor/physician if you feel unwell. Store locked up. Store in a well-ventilated place. Keep container tightly closed. Dispose of contents/container in accordance with local/regional/national/international regulations.

Altri riferimenti

Beilstein
2461627
Codice tariffe armonizzato
2903.99
TSCA
No

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