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5074-71-5 - Bis(pentafluorophenyl)phenylphosphine, 97% - Decafluorotriphenylphosphine - Phenylbis(pentafluorophenyl)phosphine - A11014 - Alfa Aesar

A11014 Bis(pentafluorophenyl)phenylphosphine, 97%

Codice CAS
5074-71-5
Sinonimi
Decafluorotriphenylphosphine
Phenylbis(pentafluorophenyl)phosphine

Dimensioni Prezzo ($) Quantità Disponibilità
0.25g 66,70
1g 206,00
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Bis(pentafluorophenyl)phenylphosphine, 97%

MDL
MFCD00000291
EINECS
225-780-1

Proprietà chimiche

Formula
C18H5F10P
Peso formula
442.20
Punto di fusione
59-64°
Punto di ebollizione
105°/0.3mm
Punto di infiammabilità
>110°(230°F)
Solubilità
Soluble in chloroform, dichloromethane, tetrahydrofuran, benzene, toluene, ethanol, methanol, and supercritical carbon dioxide.

Applicazioni

Bis(pentafluorophenyl)phenylphosphine is used as a ligand involved in the palladium-catalyzed Heck reaction of iodobenzene and styrene in compressed carbon dioxide. It is also used in the polymerization of 1,3-butadiene with Co(2-ethyl hexanoate)2.

Note

Store in a cool place. Incompatible with strong oxidizing agents, strong reducing agents, strong acids and bases.

Letteratura

Gallotta, F. D. C.; Christensen, J. H. Source identification of petroleum hydrocarbons in soil and sediments from Iguaçu River Watershed, Paraná, Brazil using the CHEMSIC method (CHEMometric analysis of Selected Ion Chromatograms). J. Chromatogr. A 2012, 1235, 149-158.

Kristensen, M.; Johnsen, A. R.; Christensen, J. H. Marine biodegradation of crude oil in temperate and Arctic water samples. J. Hazard. Mater. 2015, 300, 75-83.

Rischio GHS e dichiarazioni precauzionali

Dichiarazioni di rischio (UE): H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Dichiarazioni precauzionali: P261-P280-P305+P351+P338-P304+P340-P362-P312-P321-P405-P403+P233-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. Call a POISON CENTER or doctor/physician if you feel unwell. Specific treatment (see label). Store locked up. Store in a well-ventilated place. Keep container tightly closed. Dispose of contents/container in accordance with local/regional/national/international regulations.

Altri riferimenti

Beilstein
6253897
Codice tariffe armonizzato
2931.90
TSCA
No

Raccomandato

  • A11292

    Bromodichloromethane, 98%, stab. with potassium carbonate
  • A11422

    (Pentafluorophenyl)diphenylphosphine, 98%
  • A14377

    2-Mercaptoethylamine hydrochloride, 98+%
  • A15611

    Dodecanal, 95%, stab.
  • A15823

    (±)-Epichlorohydrin, 99%

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