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78-38-6 - Diethyl ethylphosphonate, 98% - Diethyl ethanephosphonate - Ethylphosphonic acid diethyl ester - A11046 - Alfa Aesar

A11046 Diethyl ethylphosphonate, 98%

Codice CAS
78-38-6
Sinonimi
Diethyl ethanephosphonate
Ethylphosphonic acid diethyl ester

Dimensioni Prezzo ($) Quantità Disponibilità
25g 0,00
250g 110,00
1000g 368,00
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Diethyl ethylphosphonate, 98%

MDL
MFCD00039888
EINECS
201-111-9

Proprietà chimiche

Formula
C6H15O3P
Peso formula
166.16
Punto di ebollizione
82-83°/11mm
Punto di infiammabilità
105°(221°F)
Densità
1.026
Indice di rifrazione
1.4160
Solubilità
Miscible with alcohol, ether and organic solvents. Slightly miscible with water.

Applicazioni

Diethyl ethylphosphonate is used for heavy-metal extraction and solvent separation. It is also used as a gasoline additive, antifoam agent, plasticizer and textile conditioner. Further, it serves as an antistatic agent, flame retardant and as a general reagent in phosphinoalkene and phosphinoalkyne synthesis.

Note

Incompatible with strong oxidizing agents.

Letteratura

Reaction of the lithio-derivative with diethyl carbonate followed by Wadsworth-Emmons olefination (see Appendix 1) provides a route to ɑ-methylacrylic esters in high yield: Synth. Commun., 18, 1349 (1988):

Zhu, X.; Jiang, X.; Ai, X.; Yang, H.; Cao, Y. Bis(2,2,2-Trifluoroethyl) Ethylphosphonate as Novel High-efficient Flame Retardant Additive for Safer Lithium-ion Battery. Electrochim. Acta 2015, 165, 67-71.

Hubert, J. G.; Furkert, D. P.; Brimble, M. A. Preparation of cis-gamma-Hydroxycarvone Derivatives for Synthesis of Sesterterpenoid Natural Products: Total Synthesis of Phorbin A. J. Org. Chem. 2015, 80 (4), 2231-2239.

Rischio GHS e dichiarazioni precauzionali

Dichiarazioni di rischio (UE): H302-H319-H313-H401-H411

Harmful if swallowed. Causes serious eye irritation. May be harmful in contact with skin. Toxic to aquatic life. Toxic to aquatic life with long lasting effects.

Dichiarazioni precauzionali: P273-P280-P264-P270-P305+P351+P338-P301+P312-P312-P337+P313-P330-P501a

Avoid release to the environment. Wear protective gloves/protective clothing/eye protection/face protection. Wash thoroughly after handling. Do not eat, drink or smoke when using this product. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. If eye irritation persists: Get medical advice/attention. Rinse mouth. Dispose of contents/container in accordance with local/regional/national/international regulations.

Altri riferimenti

Beilstein
1756861
Classe di rischio
9
Gruppo di imballaggio
III
Codice tariffe armonizzato
2931.90
TSCA
Yes
RTECS
SZ7925000

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