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1734-79-8 - 4-Nitrocinnamaldehyde, predominantly trans, 98% - A11467 - Alfa Aesar

A11467 4-Nitrocinnamaldehyde, predominantly trans, 98%

Codice CAS
1734-79-8
Sinonimi

Dimensioni Prezzo ($) Quantità Disponibilità
5g 86,70
25g 354,00
50g 634,00
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4-Nitrocinnamaldehyde, predominantly trans, 98%

MDL
MFCD00007379
EINECS
217-076-8

Proprietà chimiche

Formula
C9H7NO3
Peso formula
177.16
Punto di fusione
138-142°
Sensibilità
Air Sensitive
Solubilità
Insoluble in water.

Applicazioni

Doebner-Miller reaction the 4- nitrocinnamaldehyde and 2-methylaniline in concentrated HC1 give the corresponding 8-methyl-2-phenylquinoline (3: R = 4'-N02) directly. The asymmetric Friedel-Crafts-type alkylation in aqueous media reaction of 4-Nitrocinnamaldehydr with N-methyl indole using trifluoroacetic acid (TFA) salt of the PEG-PS-supported prolyl peptide having the polyleucine tether as a catalyst. 4-Nitrocinnamaldehyde has been used in the preparation of 2, 2?-[(E)-3-(4-nitrophenyl) prop-2-ene-1,1-diyl] bis(3-hydroxy-5, 5-dimethylcyclohex-2-en-1-one).

Note

Air Sensitive. Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents, air.

Letteratura

Graham J. Atwell,; Bruce C. Baguley,; William A. Denny. Potential antitumor agents. 57. 2-Phenylquinoline-8-carboxamides as minimal DNA-intercalating antitumor agents with in vivo solid tumor activity . J. Med. Chem. 1989, 32(2),396-401.

Kengo Akagawa,; Takuhiro Yamashita,; Seiji Sakamoto,; Kazuaki Kudo. Friedel-Crafts-type alkylation in aqueous media using resin-supported peptide catalyst having polyleucine. Tetrahedron Letters. 2009, 50 (40) ,5602-5604.

Rischio GHS e dichiarazioni precauzionali

Dichiarazioni di rischio (UE): H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Dichiarazioni precauzionali: P280g-P305+P351+P338

Wear protective gloves. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

Altri riferimenti

Beilstein
1565424
Codice tariffe armonizzato
2913.00
TSCA
Yes
RTECS
GD6650000

Raccomandato

  • A10293

    1,4-Dinitrobenzene, 98+%
  • A10308

    2-Nitrocinnamaldehyde, predominantly trans, 98%
  • A10429

    alpha-Methylcinnamaldehyde, predominantly (E), 97%
  • A11655

    4-Nitrobenzaldehyde, 99%
  • A12839

    trans-4-Methoxycinnamaldehyde, 98+%

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