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373-61-5 - Boron trifluoride-acetic acid complex,35-36.5% BF3 - A11471 - Alfa Aesar

A11471 Boron trifluoride-acetic acid complex,35-36.5% BF3

Codice CAS
373-61-5
Sinonimi

Dimensioni Prezzo ($) Quantità Disponibilità
250ml 49,90
1000ml 142,00
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Boron trifluoride-acetic acid complex,35-36.5% BF3

MDL
MFCD00036359
EINECS
206-768-5

Proprietà chimiche

Formula
BF3•2CH3CO2H
Peso formula
187.91
Punto di fusione
-47°
Punto di ebollizione
143-146°
Punto di infiammabilità
83°(181°F)
Densità
1.353
Indice di rifrazione
1.3670
Sensibilità
Moisture Sensitive
Solubilità
It reacts with water.

Applicazioni

It is an important raw material and intermediate used in Organic Synthesis, Pharmaceuticals, Agrochemicals and Dyestuff. It is also used as a desilylating agent. It is also been used in the protodesilylation of the phenyl group as part of the conversion of the dimethylphenylsilyl group into a hydroxyl group with retention of configuration.

Note

Keep container tightly closed in a dry and well-ventilated place. Store under inert gas. Stable, but moisture sensitive. Incompatible with water, moist air, metals, strong oxidizing agents. Store under dry atmosphere.

Letteratura

Masahito ochiai.; Kenzo sumi.; Eiichi fujita. Silicon-Assisted Ring Opening of Cyclopropyl Ketones with Boron Trifluoride-Acetic Acid Complex. Chemical and Pharmaceutical Bulletin. 1983, 31, (11), 3931-3938.

John v. Heid.; Robert levine. The Acylation of furan and thiophene with aliphatic anhydrides in the presence of boron trifluoride-etherate. J. Org. Chem. 1948, 13, (3), 409-412. Mild acid catalyst which has found use as a desilylating agent: Allylsilanes undergo desilylation, via ß-stabilized carbocations, to give alkenes with allylic rearrangement: Tetrahedron Lett., 446 (1979); J. Chem. Soc., Perkin 1, 3267 (1992). -Silyl tertiary alcohols undergo a pinacol-like rearrangement to give alkenes: Tetrahedron Lett., 22, 2321 (1981). Has been used in the protodesilylation of the phenyl group as part of the conversion of the dimethylphenylsilyl group into a hydroxyl group with retention of configuration: J. Chem. Soc., Perkin 1, 317 (1995). For reaction scheme, see Chlorodimethyl­phenyl­silane, A15638.

Rischio GHS e dichiarazioni precauzionali

Dichiarazioni di rischio (UE): H227-H302-H314-H318

Combustible liquid. Harmful if swallowed. Causes severe skin burns and eye damage. Causes serious eye damage.

Dichiarazioni precauzionali: P210u-P260u-P303+P361+P353-P305+P351+P338-P405-P501a

IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Altri riferimenti

Beilstein
3686177
Classe di rischio
8
Gruppo di imballaggio
II
Codice tariffe armonizzato
2942.00
TSCA
Yes
RTECS
ED2280000

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