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2136-75-6 - (Formylmethylene)triphenylphosphorane, 97%, may cont. up to ca 3% water - (Triphenylphosphoranylidene)acetaldehyde - A11709 - Alfa Aesar

A11709 (Formylmethylene)triphenylphosphorane, 97%, may cont. up to ca 3% water

Codice CAS
2136-75-6
Sinonimi
(Triphenylphosphoranylidene)acetaldehyde

Dimensioni Prezzo ($) Quantità Disponibilità
10g 55,10
25g 131,00
100g 436,00
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(Formylmethylene)triphenylphosphorane, 97%, may cont. up to ca 3% water

MDL
MFCD00006994
EINECS
218-375-6

Proprietà chimiche

Formula
(C6H5)3P=CHCHO
Peso formula
304.33
Punto di fusione
183-188°
Sensibilità
Air Sensitive
Solubilità
Soluble in Chloroform, Methanol.

Applicazioni

(Formylmethylene)triphenylphosphorane is used as Wittig reagent. It is also used as Pharmaceutical Intermediates. It is employed as raw material in organic Synthesis, Agrochemicals.

Note

Air Sensitive. Store at -20°C. Incompatible with strong oxidizing agents.

Letteratura

Kenji Kumazawa; Yoshiyuki Wada and Hideki Masuda. Characterization of Epoxydecenal Isomers as Potent Odorants in Black Tea (Dimbula) Infusion.J. Agric. Food Chem. 2006, 54 (13), 4795-4801.

Zh. A. Krasnaya; S. A. Burova; V. S. Bogdanov; Yu. V. Smirnova. Synthesis of δ-hetaryl-α,α-dicarbonylalkadienes and a study of their isomerization.Chemistry of Heterocyclic Compounds. 1997, 33 410-422.

Stable ylide, which undergoes Wittig olefination with aldehydes, but not usually with ketones, to give enals: J. Chem. Soc., 1266 (1961); Angew. Chem. Int. Ed., 14, 486 (1975); Tetrahedron Lett., 3071 (1977). See Appendix 1. Reaction with aldehydes generally gives the thermodynamically more stable (E)-enal. Thus glyoxal gives trans,trans-muconic dialdehyde [(E),(E)-2,4-hexadienal]: Chem. Ber., 107, 710 (1974). The following sequence leads to (Z)-enals: Chem. Ber., 115, 161 (1982):

Wittig reaction followed by reduction with DIBAL-H has been used as a route to allylic alcohols. See, e.g.: J. Org. Chem., 47, 1373 (1982).

Rischio GHS e dichiarazioni precauzionali

Dichiarazioni di rischio (UE): H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Dichiarazioni precauzionali: P261-P280a-P305+P351+P338-P304+P340-P405-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves and eye/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Altri riferimenti

Beilstein
523797
Codice tariffe armonizzato
2931.39
TSCA
No

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