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2637-34-5 - 2-Mercaptopyridine, 98% - 2-Pyridinethiol - A11741 - Alfa Aesar

A11741 2-Mercaptopyridine, 98%

Codice CAS
2637-34-5
Sinonimi
2-Pyridinethiol

Dimensioni Prezzo ($) Quantità Disponibilità
5g 18,72
25g 64,80
100g 174,40
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2-Mercaptopyridine, 98%

MDL
MFCD00006285
EINECS
220-131-9

Proprietà chimiche

Formula
C5H5NS
Peso formula
111.17
Punto di fusione
124-130°
Sensibilità
Air Sensitive
Solubilità
Slightly soluble in chloroform, methanol and dimethyl sulfoxide.

Applicazioni

Employed as a ligand in metal complexes. It can be used to coat porous media to purify plasmid DNA.

Note

Air Sensitive, keep the container tightly sealed. Store in cool place. Keep container tightly closed in a dry and well-ventilated place.

Letteratura

David B Cordes; and Lyall R Hanton. Structural invariance in silver(I) coordination networks formed using flexible four-armed thiopyridine ligands. Inorganic Chemistry. 2007, 46 (5), 1634-1644.

Alexey V Chuchuryukin et. al. Hydroxy- and mercaptopyridine pincer platinum and palladium complexes generated by silver-free halide abstraction. Inorganic Chemistry, 2006, 45 (5), 2045-2054.

S-Acyl derivatives react with Grignard reagents in a high-yielding synthesis of ketones: J. Am. Chem. Soc., 95, 4763 (1973):

Titanium enolates of S-acyl derivatives react with imines in a one pot synthesis of ß-lactams: J. Org. Chem., 57, 4155 (1992).

Rischio GHS e dichiarazioni precauzionali

Dichiarazioni di rischio (UE): H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Dichiarazioni precauzionali: P261-P280-P305+P351+P338-P304+P340-P362-P312-P321-P405-P403+P233-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. Call a POISON CENTER or doctor/physician if you feel unwell. Specific treatment (see label). Store locked up. Store in a well-ventilated place. Keep container tightly closed. Dispose of contents/container in accordance with local/regional/national/international regulations.

Altri riferimenti

Beilstein
105758
Codice tariffe armonizzato
2933.39
TSCA
Yes
RTECS
UT9600000

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