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106-95-6 - Allyl bromide, 99%, stab. with 300-1000ppm Propylene oxide - 3-Bromo-1-propene - A11766 - Alfa Aesar

A11766 Allyl bromide, 99%, stab. with 300-1000ppm Propylene oxide

Codice CAS
106-95-6
Sinonimi
3-Bromo-1-propene

Dimensioni Prezzo ($) Quantità Disponibilità
250g 25,19
1000g 67,36
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Allyl bromide, 99%, stab. with 300-1000ppm Propylene oxide

MDL
MFCD00000244
EINECS
203-446-6

Proprietà chimiche

Formula
C3H5Br
Peso formula
120.98
Punto di fusione
-119°
Punto di ebollizione
70-71°
Punto di infiammabilità
-2°(28°F)
Densità
1.398
Indice di rifrazione
1.4700
Sensibilità
Light Sensitive
Solubilità
Slightly miscible with water.

Applicazioni

Allyl bromide is used as an alkylating agent in the synthesis of pharmaceuticals, polymers, adhesives, perfumes, biochemicals and other allylic compounds. It is used as precursor for the preparation of allyliczinc bromide by reacting it with zinc. It is also used in the preparation of allylethers like allyl decyl ether, allyl benzyl ether and allyl geranyl ether. It is also used in the preparation of R enantiomer of allyl phenyl carbinol (APC) such as 1-phenyl-3-butene, which is a valuable intermediate for drugs and agro-chemicals.

Note

Moisture and light sensitive. Incompatible with oxidizing agents, alkali metals, alkaline earth metals, amides, amines and powdered metals.

Letteratura

Pandey, G.; Kant, R.; Batra, S. A general route to the synthesis of indoloazocines using allyl bromides prepared from Morita-Baylis-Hillman adducts. Tetrahedron Lett. 2015, 56 (7), 930-933.

Fananas-Mastral, M.; Vitale, R.; Perez, M.; Feringa, B. L. Enantioselective Synthesis of All-Carbon Quaternary Stereogenic Centers via Copper-Catalyzed Asymmetric Allylic Alkylation of (Z)-Allyl Bromides with Organolithium Reagents. Chem. Eur. J. 2015, 21 (11), 4209-4212.

Rischio GHS e dichiarazioni precauzionali

Dichiarazioni di rischio (UE): H225-H301-H331-H340-H350-H314-H400

Highly flammable liquid and vapour. Toxic if swallowed. Toxic if inhaled. May cause genetic defects. May cause cancer. Causes severe skin burns and eye damage. Very toxic to aquatic life.

Dichiarazioni precauzionali: P210-P260-P201-P261-P301+P310-P303+P361+P353-P305+P351+P338-P301+P330+P331-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not breathe dust/fume/gas/mist/vapours/spray. Obtain special instructions before use. Avoid breathing dust/fume/gas/mist/vapours/spray. IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Rinse mouth. Do NOT induce vomiting. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Altri riferimenti

Merck
14,288
Classe di rischio
3
Gruppo di imballaggio
I
Codice tariffe armonizzato
2903.39
TSCA
Yes
RTECS
UC7090000

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