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121-69-7 - N,N-Dimethylaniline, 99% - A11916 - Alfa Aesar

A11916 N,N-Dimethylaniline, 99%

Codice CAS
121-69-7
Sinonimi

Dimensioni Prezzo ($) Quantità Disponibilità
100ml 18,64
500ml 20,08
2500ml 47,97
10000ml 170,98
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N,N-Dimethylaniline, 99%

MDL
MFCD00008304
EINECS
204-493-5

Proprietà chimiche

Formula
C8H11N
Peso formula
121.18
Punto di fusione
Punto di ebollizione
193°
Punto di infiammabilità
62°(143°F)
Densità
0.956
Indice di rifrazione
1.5580
Solubilità
Miscible with water, ethanol, ether, acetone, chloroform, benzene and alkaline.

Applicazioni

N,N-Dimethylaniline acts as a precursor to triarylmethane dyes such as crystal violet and malachite green. It is also used in the synthesis of vanillin, methyl violet, and Michler's ketone. Further, it is used as a hardener for plastic resins and an acid scavenger in the manufacture of semisynthetic penicillins and cephalosporins. In addition to this, it is used as a promoter in the curing of polyester and vinyl ester resins.

Note

Incompatible with strong oxidizing agents, Strong acids, acid chlorides, acid anhydrides, chloroformates and halogens.

Letteratura

Base for acylation reactions; see, e.g.: Org. Synth. Coll., 3, 142 (1955), 4, 263 (1963); 5, 171 (1973).

For an example of ortho-lithiation, followed by Pd-catalyzed coupling wth a vinyl bromide, see: Org. Synth. Coll., 7, 172 (1990).

The AlCl3 complex with has been used to cleave benzyl and allyl ethers: Tetrahedron Lett., 32, 1321 (1991).

Brown, T. A.; Chen, H.; Zare, R. N. Detection of the Short-Lived Radical Cation Intermediate in the Electrooxidation of N, N-Dimethylaniline by Mass Spectrometry. Angew. Chem. Int. Ed. 2015, 127 (38), 11335-11337.

Watode, B. D.; Hudge, P. G.; Shinde, M. N.; Talware, R. B.; Kumbharkhane, A. C. Dielectric relaxation study of aniline, N-methylaniline and N,N-dimethylaniline and alcohol in 1, 4-dioxane using picosecond time-domain reflectometry. Phys. Chem. Liq. 2015, 53 (2), 252-263.

Rischio GHS e dichiarazioni precauzionali

Dichiarazioni di rischio (UE): H301-H311-H331-H351-H227-H411

Toxic if swallowed. Toxic in contact with skin. Toxic if inhaled. Suspected of causing cancer. Combustible liquid. Toxic to aquatic life with long lasting effects.

Dichiarazioni precauzionali: P210-P201-P261-P273-P280-P281-P301+P310-P361-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Obtain special instructions before use. Avoid breathing dust/fume/gas/mist/vapours/spray. Avoid release to the environment. Wear protective gloves/protective clothing/eye protection/face protection. Use personal protective equipment as required. IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. Remove/Take off immediately all contaminated clothing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Altri riferimenti

Merck
14,3234
Beilstein
507140
Classe di rischio
6.1
Gruppo di imballaggio
II
Codice tariffe armonizzato
2921.42
TSCA
Yes
RTECS
BX4725000

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