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17564-64-6 - N-(Chloromethyl)phthalimide, 97% - A12018 - Alfa Aesar

A12018 N-(Chloromethyl)phthalimide, 97%

Codice CAS
17564-64-6
Sinonimi

Dimensioni Prezzo ($) Quantità Disponibilità
25g 58,50
100g 221,00
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N-(Chloromethyl)phthalimide, 97%

MDL
MFCD00005898
EINECS
241-541-4

Proprietà chimiche

Formula
C9H6ClNO2
Peso formula
195.61
Punto di fusione
131-135°
Solubilità
Insoluble in water.

Applicazioni

It is used as an agrochemical and medicine intermediates and is used in organic synthesis. Microporous membranes prepared from chemically modified polysulfone, which is a derivative of this compound have better streaming potential.

Note

Store in cool place. Keep away from oxidizing agents. Incompatible with bases.

Letteratura

Ekkehard Hinke.; Eberhard Staude. Streaming potential of microporous membranes made from homogeneously functionalized polysulfone. J. Appl. Polym. Sci. 1991, 42 (11),2951-2958.

M. Hariharan.; S. Chaberek.; A. E. Martella. Synthesis of Phosphonopeptide Derivatives. Synth. Commun. 1973, 3 (5),375-379.

Reagent for carboxyl protection, e.g. in peptide synthesis, by reaction in the presence of an amine: Rec. Trav. Chim., 82, 941 (1963); or with KF in DMF: Synth. Commun., 8, 515 (1978). The phthalimidomethyl ester can be cleaved in various ways including hydrazinolysis, HBr in acetic acid or Zn/AcOH. See also N-(Hydroxymethyl)­phthalimide, B21292 and Appendix 6.

Also reported for the protection of thiols as the S-phthalimidomethyl (Pim) derivative. Cleavage is by hydrazinolysis, followed by Hg(II), Cu(II) or I2: Chem. Lett., 2139 (1994).

Reagent for the amidomethylation of aromatic systems. For reviews of amidomethylation, see: Org. React., 14, 52 (1965); Synthesis, 49 (1970); 85, 181 (1984).

Rischio GHS e dichiarazioni precauzionali

Dichiarazioni di rischio (UE): H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Dichiarazioni precauzionali: P260-P201-P280g-P304+P340-P405-P501a

Do not breathe dust/fume/gas/mist/vapours/spray. Obtain special instructions before use. Wear protective gloves. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Altri riferimenti

Beilstein
140942
Codice tariffe armonizzato
2925.19
TSCA
Yes

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