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107-15-3 - Ethylenediamine, 99% - 1,2-Diaminoethane - 1,2-Ethanediamine - A12132 - Alfa Aesar

A12132 Ethylenediamine, 99%

Codice CAS
107-15-3
Sinonimi
1,2-Diaminoethane
1,2-Ethanediamine

Dimensioni Prezzo ($) Quantità Disponibilità
100ml 16,20
500ml 26,80
2500ml 78,00
*4x2.5L 272,00
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Ethylenediamine, 99%

MDL
MFCD00008204
EINECS
203-468-6

Proprietà chimiche

Formula
C2H8N2
Peso formula
60.10
Punto di fusione
8-11°
Punto di ebollizione
117-118°
Punto di infiammabilità
38°(100°F)
Densità
0.899
Indice di rifrazione
1.4565
Sensibilità
Air Sensitive
Solubilità
Miscible with water and alcohol. Slightly miscible with ether.

Applicazioni

Ethylenediamine is a strongly basic amine useful as a building block in chemical synthesis. It is used as a solvent to dissolve proteins such as albumins and casein. It is widely used for color photography developers, binders, adhesives, fabric softeners, curing agents for epoxys and dyes. As a corrosion inhibitor, it plays a vital role in paints and coolants. It is used as an intermediate in the preparation of polyamide resins, fuel additives and lubricants. It acts as a precursor for many polymers like polyurethane fibers and poly(amidoamine), ethylenediamine dihydroiodide (EDDI) as well as the bleaching activator, tetraacetylethylenediamine. It is an important chelating ligand used in the preparation of coordination compounds viz. tris(ethylenediamine)cobalt(III) chloride. It is also involved in the manufacture of many industrial chemicals and forms derivatives with carboxylic acids, nitriles, alcohols, alkylating agents, carbon disulfide, aldehydes and ketones. It is a basic building block to prepare heterocyclic compound such as imidazolidines.

Note

Air and moisture sensitive. Keep the container tightly closed in a dry and well-ventilated place. Incompatible with oxidizing agents, phosphorus halides, aldehydes and organic halides.

Letteratura

The Li derivative in excess amine is a strong base for the rearrangement of primary allylic alcohols to the isomeric aldehydes in high yield: J. Chem. Soc., Chem. Commun., 812 (1985).

At high temperatures, reduces nitroarenes to azo-compounds. Reaction does not occur for nitro-compounds with o-substituents or p-amino-substituents: J. Org. Chem., 49, 1215 (1984).

The ethylenediamine complex of Cr2+ reduces aryl bromides to the hydrocarbons. For an example, see: Org. Synth. Coll., 6, 821 (1988).

Xue, B.; Zhu, J.; Liu, N.; Li, Y. Facile functionalization of graphene oxide with ethylenediamine as a solid base catalyst for Knoevenagel condensation reaction. Catal. Commun. 2015, 64, 105-109.

Moradpour, A.; Ghaffarinejad, A.; Maleki, A.; Eskandarpour, V.; Motaharian, A. Low loaded palladium nanoparticles on ethylenediamine-functionalized cellulose as an efficient catalyst for electrochemical hydrogen production. RSC Adv. 2015, 5 (86), 70668-70674.

Rischio GHS e dichiarazioni precauzionali

Dichiarazioni di rischio (UE): H226-H302-H312-H314-H334-H317

Flammable liquid and vapour. Harmful if swallowed. Harmful in contact with skin. Causes severe skin burns and eye damage. May cause allergy or asthma symptoms or breathing difficulties if inhaled. May cause an allergic skin reaction.

Dichiarazioni precauzionali: P210-P260u-P303+P361+P353-P305+P351+P338-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Altri riferimenti

Merck
14,3795
Beilstein
605263
Classe di rischio
8
Gruppo di imballaggio
II
Codice tariffe armonizzato
2921.21
TSCA
Yes
RTECS
KH8575000

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