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Diethyl diallylmalonate is the starting material for enantioselective synthesis of carbocyclic nucleoside analogues. It is also used as Low catalyst loading in ring-closing metathesis reaction. Cationic nickel (with monodentate phosphoramidites and Wilke?s azaphospholene as ligands) catalyzed cycloisomerisation of diethyl diallylmalonate has been reported.
Piotr Nieczypor.; Wlodzimierz Buchowicz.; Wim J.N Meester.; Floris P.J.T Rutjes.; Johannes C Mol. Synthesis and application of a new polystyrene-supported ruthenium carbene catalyst for alkene metathesis. Tetrahedron Lett.. 2001, 42 (40),7103-7105.
Matthias Scholl.; Sheng Ding.; Choon Woo Lee.; Robert H. Grubbs. Synthesis and Activity of a New Generation of Ruthenium-Based Olefin Metathesis Catalysts Coordinated with 1,3-Dimesityl-4,5-dihydroimidazol-2-ylidene Ligands.Org. Lett. 1999, 1 (6),953-956.
Starting material for enantioselective synthesis of carbocyclic nucleoside analogues: J. Org. Chem., 61, 7963 (1996).
Dichiarazioni di rischio (UE): H315-H319-H335
Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.
Dichiarazioni precauzionali: P261-P280a-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves and eye/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.