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1600-27-7 - Mercury(II) acetate, 98+% - Acetic acid mercury(II) salt - Mercuric acetate - A12478 - Alfa Aesar

A12478 Mercury(II) acetate, 98+%

Codice CAS
1600-27-7
Sinonimi
Acetic acid mercury(II) salt
Mercuric acetate

Dimensioni Prezzo ($) Quantità Disponibilità
25g 23,60
100g 55,60
500g 168,00
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Mercury(II) acetate, 98+%

MDL
MFCD00012165
EINECS
216-491-1

Proprietà chimiche

Formula
C4H6HgO4
Peso formula
318.68
Punto di fusione
179-182°
Densità
3.28
Sensibilità
Light Sensitive
Solubilità
Soluble in water.

Applicazioni

Mercury(II) acetate is used as a reagent to prepare organomercury compounds and to remove the acetamidomethyl protecting group in organic synthesis. It is also involved in the oxymercuration reactions as well as to prepare dithiocarbonates from thiocarboantes.It finds application as a catalyst in organic synthesis, pharmaceuticals and absorption of ethylene.

Note

Light sensitive. Incompatible with strong oxidizing agents, strong acids and strong bases.

Letteratura

The solvomercuration of alkenes by Hg(OAc)2, with demercuration by NaBH4, is a useful method for the Markovnikov hydration of alkenes; reviews: Angew. Chem. Int. Ed., 17, 27 (1978); Tetrahedron, 38, 1713 (1982). See, e.g.: Org. Synth. Coll., 6, 766 (1988):

Intramolecular oxy- or amino-mercuration is a useful route to oxygen or nitrogen heterocycles: J. Heterocycl. Chem., 11, 771 (1974); 13, 349 (1976); 15, 1313 (1978):

For an improved method for the synthesis of substituted pyrrolidines using TBTH as reducing agent, avoiding the reaction reversal encountered with borohydride, see: Synth. Commun., 26, 1507 (1996).

Mercuration/demercuration of aliphatic isocyanates provides a mild route to primary amines: Tetrahedron Lett., 36, 8859 (1995).

For a review of organomercurials in synthesis, see: Tetrahedron, 38, 1713 (1982).

Schmidt, E. Y.; Vasil’tsov, A. M.; Zorina, N. V.; Ivanov, A. V.; Mikhaleva, A. I.; Trofimov, B. A. Devinylation of N-vinylpyrroles using mercury(II) acetate. Chem. Heterocycl. Compd. 2012, 47 (10), 1300-1303.

Dehghanpour, S.; Jahani, K.; Mahmoudi, A.; Babakhodaverdi, M.; Notash, B. In situ hydrothermal synthesis of 2D mercury(I)-organic framework from 3-aminopyrazine-2-carboxylic acid and mercury(II) acetate. Inorg. Chem. Commun. 2012, 25, 79-82.

Rischio GHS e dichiarazioni precauzionali

Dichiarazioni di rischio (UE): H300-H310-H330-H373-H400-H410

Fatal if swallowed. Fatal in contact with skin. Fatal if inhaled. May cause damage to organs through prolonged or repeated exposure. Very toxic to aquatic life. Very toxic to aquatic life with long lasting effects.

Dichiarazioni precauzionali: P273-P280h-P309-P310-P302+P352-P501a

Avoid release to the environment. Wear protective gloves/clothing. IF exposed or if you feel unwell: Immediately call a POISON CENTER or doctor/physician. IF ON SKIN: Wash with plenty of soap and water. Dispose of contents/container in accordance with local/regional/national/international regulations.

Altri riferimenti

Merck
14,5873
Beilstein
3563831
Classe di rischio
6.1
Gruppo di imballaggio
II
Codice tariffe armonizzato
2852.10
TSCA
Yes
RTECS
AI8575000

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