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It is considered as a more reactive reagent than Chlorotriphenylmethane, for the preparation of trityl esters. It is also used in one-pot conversion of amino acids to their N-trityl derivatives involving N,O-ditritylation and selective methanolysis of the trityl ester.
Alan C. Scott and John M. Tedder. The induced homolysis of bromotriphenylmethane by a nitroxide.J. Chem. Soc., Chem. Commun.,1979(2), 64b-65.
A. E. Arbuzov and M. Sh. Bastonova. The tautomerism of carbostyril derivatives.Bulletin of the Academy of Sciences of the USSR, Division of chemical science,1952,1(5), 747-754.
More reactive reagent than Chlorotriphenylmethane, A11799 for the preparation of trityl esters: J. Org. Chem., 27, 3595 (1962). One-pot conversion of amino acids to their N-trityl derivatives involves N,O-ditritylation and selective methanolysis of the trityl ester: Synthesis, 198 (1989). See also Appendix 6.
Dichiarazioni di rischio (UE): H314-H318
Causes severe skin burns and eye damage. Causes serious eye damage.
Dichiarazioni precauzionali: P260u-P303+P361+P353-P305+P351+P338-P301+P330+P331-P405-P501a
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.