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Diisopropyl methylphosphonate is used as a precursor to prepare beta-keto phosphonates. It acts as an intermediate for Horner-Wadsworth-Emmons olefination of carbonyl compounds.
Reacts with esters giving ß-keto phosphonates, useful intermediates for Horner-Wadsworth-Emmons olefination of carbonyl compounds, cf Dimethyl methylphosphonate, A14268.
Terzic, O.; Gregg, H.; Voogt, P. Identification of chemicals relevant to the Chemical Weapons Convention using the novel sample-preparation methods and strategies of the Mobile Laboratory of the Organization for the Prohibition of Chemical Weapons. TrAC, Trends Anal. Chem. 2015, 65, 151-166.
Maza, W. A.; Vetromile, C. M.; Kim, C.; Xu, X.; Zhang, X. P.; Larsen, R. W. Spectroscopic Investigation of the Noncovalent Association of the Nerve Agent Simulant Diisopropyl Methylphosphonate (DIMP) with Zinc(II) Porphyrins. J. Phys. Chem. A 2013, 117 (44), 11308-11315.
Dichiarazioni di rischio (UE): H302-H315-H319-H335
Harmful if swallowed. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.
Dichiarazioni precauzionali: P261-P280a-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves and eye/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.