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104-54-1 - Cinnamyl alcohol, 98% - 3-Phenyl-2-propen-1-ol - A13025 - Alfa Aesar

A13025 Cinnamyl alcohol, 98%

Codice CAS
104-54-1
Sinonimi
3-Phenyl-2-propen-1-ol

Dimensioni Prezzo ($) Quantità Disponibilità
250g 30,00
1000g 94,00
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Cinnamyl alcohol, 98%

MDL
MFCD00002921
EINECS
203-212-3

Proprietà chimiche

Formula
C9H10O
Peso formula
134.18
Punto di fusione
32-35°
Punto di ebollizione
257-258°
Punto di infiammabilità
126°(258°F)
Densità
1.044
Solubilità
Soluble in water 1.8 g/L (20°C).

Applicazioni

Cinnamyl alcohol is an important raw material and intermediate used in organic Synthesis, pharmaceuticals, agrochemicals and dyestuff. It is also used in perfumery and as well as a deodorant.

Note

Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Stable under recommended storage conditions. Incompatible with strong oxidizing agents.

Letteratura

E Armengol.; ML Cano.; A Corma.; H García. Mesoporous aluminosilicate MCM-41 as a convenient acid catalyst for Friedel-Crafts alkylation of a bulky aromatic compound with cinnamyl alcohol. Journal of the Chemical Society, Chemical Communications.19957 (1), 519-520.

RL Mansell.; GG Gross.; J Stöckigt.; H Franke.; MH Zenk. Purification and properties of cinnamyl alcohol dehydrogenase from higher plants involved in lignin biosynthesis. Phytochemistry. 19747 (1), 519-520.

Protection of carboxylic acids as cinnamyl esters has been reported: J. Chem. Soc., Chem. Commun., 707 (1996). They can be cleaved under neutral conditions with Hg(II) or KSCN: Tetrahedron Lett., 2081 (1977).

Allylic alcohols react with primary or secondary amines in the presence of SnCl2 and a Pd(0) catalyst to give allylic amines regioselectively: Chem. Lett., 1121 (1995):

Rischio GHS e dichiarazioni precauzionali

Dichiarazioni di rischio (UE): H302-H315-H319-H317

Harmful if swallowed. Causes skin irritation. Causes serious eye irritation. May cause an allergic skin reaction.

Dichiarazioni precauzionali: P260-P201-P280h-P304+P340-P405-P501a

Do not breathe dust/fume/gas/mist/vapours/spray. Obtain special instructions before use. Wear protective gloves/clothing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Altri riferimenti

Merck
14,2302
Beilstein
1903999
Codice tariffe armonizzato
2906.29
TSCA
Yes
RTECS
GE2200000

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