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4336-70-3 - (Cyanomethyl)triphenylphosphonium chloride, 98+% - A13096 - Alfa Aesar

A13096 (Cyanomethyl)triphenylphosphonium chloride, 98+%

Codice CAS
4336-70-3
Sinonimi

Dimensioni Prezzo ($) Quantità Disponibilità
5g 22,40
25g 60,20
100g 209,00
500g 895,00
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(Cyanomethyl)triphenylphosphonium chloride, 98+%

MDL
MFCD00031672
EINECS
224-383-0

Proprietà chimiche

Formula
NCCH2P(C6H5)3Cl
Peso formula
337.79
Punto di fusione
ca 270° dec.
Sensibilità
Hygroscopic

Letteratura

Forms a moderately stable crystalline ylide which reacts with aldehydes to give ɑß-unsaturated nitriles, predominantly as their (Z)-isomers: Chem. Ber., 94, 578 (1961); J. Chem. Soc., 1266 (1961); Appendix 1.

/n

Further deprotonation of the phosphorane with sodium bis(trimethylsilyl)amide followed by C-alkylation generates a homologated phosphorane: Angew. Chem. Int. Ed., 26, 79 (1987).

/n

Reaction of the ylide with carboxylic acids in the presence of EDCI (1-(3-Dimethyl­aminopropyl)-3-ethyl­carbodiimide hydrochloride, A10807) and DMAP, followed by ozonolysis of the resulting acylphosphoranes, provides a novel route to the homologous ɑ-keto esters: J. Org. Chem., 59, 4364 (1994):

/n

/n

Rischio GHS e dichiarazioni precauzionali

Dichiarazioni di rischio (UE): H331-H302-H312-H315-H319-H335

Toxic if inhaled. Harmful if swallowed. Harmful in contact with skin. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Dichiarazioni precauzionali: P261-P280-P305+P351+P338-P304+P340-P311-P362-P301+P312-P312-P405-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/physician. Take off contaminated clothing and wash before reuse. IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Altri riferimenti

Beilstein
6222047
Classe di rischio
6.1
Gruppo di imballaggio
III
Codice tariffe armonizzato
2931.90
TSCA
No
RTECS
TA2075000

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