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96-33-3 - Methyl acrylate, 99%, stab. with ca 15ppm 4-methoxyphenol - Acrylic acid methyl ester - Methyl propenoate - A13128 - Alfa Aesar

A13128 Methyl acrylate, 99%, stab. with ca 15ppm 4-methoxyphenol

Codice CAS
96-33-3
Sinonimi
Acrylic acid methyl ester
Methyl propenoate

Dimensioni Prezzo ($) Quantità Disponibilità
100ml 14,94
500ml 26,82
2500ml 68,19
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Methyl acrylate, 99%, stab. with ca 15ppm 4-methoxyphenol

MDL
MFCD00008627
EINECS
202-500-6

Proprietà chimiche

Formula
CH2=CHCO2CH3
Peso formula
86.09
Punto di fusione
-75°
Punto di ebollizione
79-81°
Punto di infiammabilità
-3°(26°F)
Densità
0.956
Indice di rifrazione
1.4030
Sensibilità
Light Sensitive
Solubilità
Miscible with water.

Applicazioni

Methyl acrylate is a monomer used in the preparation of polymers having rigid, flexible, ionic, nonionic, hydrophobic, or hydrophilic properties. It is involved in the production of acrylate fiber, which is used to weave synthetic carpets. It plays an important role as a reagent in the synthesis of pharmaceutical intermediates and alfa ω-dicarboxylic acid esters. It is a good nucleophile and a michael acceptor to prepare polyamidoamine (PAMAM) dendrimers.

Note

Light sensitive. Incompatible with oxidizing agents and peroxides.

Letteratura

Dai, S.; Sui, X.; Chen, C. Highly Robust Palladium(II) α-Diimine Catalysts for Slow-Chain-Walking Polymerization of Ethylene and Copolymerization with Methyl Acrylate. Angew. Chem. Int. Ed. 2015, 54 (34), 9948-9953.

Xia, G.; Jiang, X.; Zhou, L.; Liao, Y.; Wang, H.; Pu, Q.; Zhou, J. Synergic effect of methyl acrylate and N-cetylpyridinium bromide in N-cetyl-3-(2-methoxycarbonylvinyl) pyridinium bromide molecule for X70 steel protection. Corros. Sci. 2015, 94, 224-236.

Rischio GHS e dichiarazioni precauzionali

Dichiarazioni di rischio (UE): H225-H302-H312-H332-H315-H319-H317-H335

Highly flammable liquid and vapour. Harmful if swallowed. Harmful in contact with skin. Harmful if inhaled. Causes skin irritation. Causes serious eye irritation. May cause an allergic skin reaction. May cause respiratory irritation.

Dichiarazioni precauzionali: P210-P261-P280-P240-P303+P361+P353-P305+P351+P338-P304+P340-P362-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. Ground/bond container and receiving equipment. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Altri riferimenti

Merck
14,6011
Beilstein
605396
Classe di rischio
3
Gruppo di imballaggio
II
Codice tariffe armonizzato
2916.12
TSCA
Yes
RTECS
AT2800000

Raccomandato

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  • A13030

    Methyl methacrylate, 99%, stab.
  • A13058

    Acrylonitrile, 99+%, stab. with ca 40ppm 4-methoxyphenol
  • A15493

    Ethyl acrylate, 99%, stab. with ca 20ppm 4-methoxyphenol
  • A18481

    Styrene, 99%, stab. with 10-15ppm 4-tert-butylcatechol

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