Accetto Utilizziamo cookies per migliorare il nostro servizio e realizzare statistiche. Questa funzione puó essere disattivata cambiando la configurazione del browser. Continuando a navigare senza modificare questi parametri, consideriamo che l’uso di cookies sia accettato
Cyclopropyl methyl ketone was used in the preparation of homoallylic alcohols. Acetylcyclopropane is used as an intermediate for the manufacturing pharmaceuticals, agrochemicals and other organic compounds.
L. S. Bartell.; J. P. Guillory.; Andrea T. Parks. Electron Diffraction Study of the Structure and Conformational Behavior of Cyclopropyl Methyl Ketone and Cyclopropanecarboxylic Acid Chloride1a. J. Phys. Chem. 1965, 69, (9), 3043-3048.
William G. Dauben.; Richard E. Wolf. Transition-state conformations in the reductive opening of cyclopropyl methyl ketones. J. Org. Chem. 1970, 35, (7), 2361-2367.
Various cyclopropyl ketones have been used in the synthesis of δ-ketonic phosphonium salts which, protected as thioacetals, have found use in the Wittig reaction: Synthesis, 648 (1987):
Dichiarazioni di rischio (UE): H225-H301-H315-H319-H335
Highly flammable liquid and vapour. Toxic if swallowed. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.
Dichiarazioni precauzionali: P210-P301+P310a-P303+P361+P353-P305+P351+P338-P405-P501a
Keep away from heat/sparks/open flames/hot surfaces. - No smoking. IF SWALLOWED: Immediately call a POISON CENTER/doctor IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.