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3,5-Dibromosalicylaldehyde reacts with alkyl cyanoacetates in the presence of ammonium acetate to yield 4H- chromenes. It can be used in the synthesis of Schiff base and can be used as reactant for synthesis of Schiff base ligands which forms mononuclear complexes with copper(II), nickel(II), zinc(II) and cobalt(II).
Yongming Cui; Xiongwei Dong; Yuguang Li; Zuowen Li; Wu Chen. Synthesis, structures and urease inhibition studies of Schiff base metal complexes derived from 3,5-dibromosalicylaldehyde.European Journal of Medicinal Chemistry.2012, 58 323-331.
L Tian; Z Shang; X Zheng; Y Sun; Y Yu; Bochu Qian and Xueli Liu. Synthesis, characterization and biological activity of diphenyltin(IV) complexes of N-(3,5-dibromosalicylidene)-α-amino acid and their diphenyltin dichloride adducts.Applied Organometallic Chemistry.2006, 20 74-80.
Dichiarazioni di rischio (UE): H315-H319-H335
Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.
Dichiarazioni precauzionali: P261-P280a-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves and eye/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.