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The reactions of 1-hexanol with benzylamine and with 4-methylbenzylamine led to the corresponding imines in moderate yields. 4-methylbenzylamine in ethanol/water solution (1:4) as simultaneously absorbing and buffering background electrolyte with detection at 210 nm was found suitable for determination of the individual compounds in determination by capillary zone electrophoresis with indirect detection. Synthesis of benzimidazoles uses 4-methylbenzylamine (R 1 =4-MeBn) and 4-chlorophenyl isothiocyanate (R 2 =4-ClPh) as building blocks.
Viktor Krch?ák,; Jennifer Smith,; Josef Vágner. A solid phase traceless synthesis of 2-arylaminobenzimidazoles. Tetrahedron Letters. 2001, 42 (9), 1627-1630.
Nada Reichová,; Ji?í Pazourek,; Pavla Polášková andJosef Havel. Electrophoretic behavior of adamantane derivatives possessing antiviral activity and their determination by capillary zone electrophoresis with indirect detection. Electrophoresis. 2002, 23 (2), 259-262.
Dichiarazioni di rischio (UE): H227-H314-H318
Combustible liquid. Causes severe skin burns and eye damage. Causes serious eye damage.
Dichiarazioni precauzionali: P210u-P260u-P303+P361+P353-P305+P351+P338-P405-P501a
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.