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The Arthrobacter sp. is able to grow with (+ I-,(-)-1-phenylethanol or the racemic mixture as sole source of carbon. Growth is most rapid with the (-)-isomer, doubling time 12 h. Lipases show good activity and, in some cases, improved enantioselectivity when employed in pure ionic liquids for dynamic kinetic resolution of 1-phenylethanol by transesterification.
Roger E. Cripps,; Peter W. Trudgill,; John G. Whateley. The Metabolism of 1-Phenylethanol and Acetophenone by Nocardia T5 and an Arthrobacter Species. European Journal of Biochemistry. 1978, 86 (1), 175-186.
Priska Hubera,; Svetoslav Bratovanova,; Stefan Bienz,; Christoph Syldatk,; Markus Pietzsch.Chiral silicon groups as auxiliaries for enantioselective synthesis: access to optically active silanes by biotransformation and the enantiospecific preparation of (R)-(+)-1-phenylethanol . Tetrahedron: Asymmetry. year of publication , 7(1), 69-78.
Dichiarazioni di rischio (UE): H227-H302-H315-H318-H335
Combustible liquid. Harmful if swallowed. Causes skin irritation. Causes serious eye damage. May cause respiratory irritation.
Dichiarazioni precauzionali: P210u-P261-P280a-P305+P351+P338-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves and eye/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.