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α,α,α',α'-Tetrabromo-o-xylene reacts with 5endo,6endo-bis-chlormethyl-norborn-2-en to obtain trans/cis-2,3-bis(chloromethyl)-1,4-methano-1,2,3,4-tetrahydroanthracene. Further, it is involved in the preparation of 1-(3-butenyl)-2-(deuteriomethyl)benzene by reacting with allylmagnesium bromide. In addition this, it is used to prepare exo-benzocyclobuteno-1,2,3,4-tetrahydro-1,4-methanoanthracene by reacting with exo-1,4,4a,8b-tetrahydro-1,4-methanobiphenylene.
Tian, Y.; Uchida, K.; Kurata, H.; Hirao, Y.; Nishiuchi, T.; Kubo, T. Design and Synthesis of New Stable Fluorenyl-Based Radicals. J. Am. Chem. Soc. 2014, 136 (36), 12784-12793.
Song, C. L.; Ma, C. B.; Yang, F.; Zeng, W. J.; Zhang, H. L.; Gong, X. Synthesis of Tetrachloro-azapentacene as an Ambipolar Organic Semiconductor with High and Balanced Carrier Mobilities. Org. Lett. 2011, 13 (11), 2880-2883.
Dichiarazioni di rischio (UE): H314-H318-H317-H335
Causes severe skin burns and eye damage. Causes serious eye damage. May cause an allergic skin reaction. May cause respiratory irritation.
Dichiarazioni precauzionali: P260u-P303+P361+P353-P305+P351+P338-P301+P330+P331-P405-P501a
Do not breathe dusts or mists. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.