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75-03-6 - Iodoethane, 98+%, stab. with copper - Ethyl iodide - A14444 - Alfa Aesar

A14444 Iodoethane, 98+%, stab. with copper

Codice CAS
75-03-6
Sinonimi
Ethyl iodide

Dimensioni Prezzo ($) Quantità Disponibilità
100g 31,93
500g 111,24
2500g 432,60
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Iodoethane, 98+%, stab. with copper

MDL
MFCD00001091
EINECS
200-833-1

Proprietà chimiche

Formula
CH3CH2I
Peso formula
155.97
Punto di fusione
-108°
Punto di ebollizione
70-73°
Punto di infiammabilità
>73°(163°F)
Densità
1.95
Indice di rifrazione
1.5120
Sensibilità
Moisture & Light Sensitive
Solubilità
Miscible with water.

Applicazioni

Iodoethane is an excellent ethylating agent used in organic synthesis to introduce an ethyl group into a compound. It reacts with magnesium to form the Grignard reagent, ethylmagnesium iodide which is used in organic synthesis. It is involved in the preparation of 1-ethyl-3-nitro-2-phenyl-indole and also serves as hydrogen radical promoter.

Note

Moisture and light sensitive. Keep the container tightly closed in a dry and well-ventilated place. Incompatible with strong bases, strong oxidizing agents and magnesium.

Letteratura

Nijamudheen, A.; Datta, A. Mechanism for C-I Bond Dissociation in Iodoethane, Iodobenzene, and Iodoethene for the C-C Cross Coupling Reactions over Gold Clusters. J. Phys. Chem. C 2013, 117 (41), 21433-21440.

Ljubic, I.; Matasovic, B.; Bonifacic, M. An efficient buffer-mediated control between free radical substitution and proton-coupled electron transfer: dehalogenation of iodoethane by the alpha-hydroxyethyl radical in aqueous solution. Phys. Chem. Chem. Phys. 2013, 15 (41), 18001-18011.

Rischio GHS e dichiarazioni precauzionali

Dichiarazioni di rischio (UE): H334-H315-H319-H317-H302-H335

May cause allergy or asthma symptoms or breathing difficulties if inhaled. Causes skin irritation. Causes serious eye irritation. May cause an allergic skin reaction. Harmful if swallowed. May cause respiratory irritation.

Dichiarazioni precauzionali: P285-P261-P280-P305+P351+P338-P304+P340-P342+P311-P362-P301+P312-P405-P501a

In case of inadequate ventilation wear respiratory protection. Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. If experiencing respiratory symptoms: Call a POISON CENTER or doctor/physician. Take off contaminated clothing and wash before reuse. IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Altri riferimenti

Merck
14,3813
Beilstein
505934
Codice tariffe armonizzato
2903.39
TSCA
Yes
RTECS
KI4750000

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