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10035-10-6 - Hydrogen bromide, 33% w/w (45% w/v) soln. in acetic acid - Hydrobromic acid acetic acid solution - A14475 - Alfa Aesar

A14475 Hydrogen bromide, 33% w/w (45% w/v) soln. in acetic acid

Codice CAS
10035-10-6
Sinonimi
Hydrobromic acid acetic acid solution

Dimensioni Prezzo ($) Quantità Disponibilità
100ml 34,30
500ml 117,00
2500ml 456,00
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Hydrogen bromide, 33% w/w (45% w/v) soln. in acetic acid

MDL
MFCD00011323
EINECS
233-113-0

Proprietà chimiche

Formula
BrH
Peso formula
80.92
Punto di infiammabilità
65°(149°F)
Densità
1.40
Solubilità
Miscible with water, alcohol and organic solvents.

Applicazioni

Hydrobromic acid is an indispensable raw material for organic intermediates, inorganic pharmaceuticals, photosensitive materials, dyes and medicines. It is also used in the production of bromine compounds. It is used as an important agent in the industrial processes of isomerization, polymerization, hydration and dehydration and esterification reactions. It plays an essential role for the extraction of mercury from the cinnebar ore.

Note

Air and light sensitive. Incompatible with strong bases, strong oxidizing agents, ammonia, ozone, fluorine, potassium permanganate, amines, alcohols and metals.

Letteratura

Preferred reagent for the non-hydrogenolytic cleavage of the N-benzyloxycarbonyl (Cbz, Z) group in peptide synthesis: J. Org. Chem., 17, 1564 (1952). For peptide reagents, see Appendix 6.

Used in combination with Paraformaldehyde, A11313, or 1,3,5-Trioxane, A15639, for the bromomethylation of aromatics: J. Org. Chem., 58, 1262 (1993); Synlett, 55 (1989). For N-bromomethylation of phthalimide and other imides, see: Synlett, 933 (1994).

For use in the bromoacetoxylation of (S)-(+)-1,2-Propanediol, B21773, as an example of the conversion of chiral vic-diols to epoxides with retention of configuration, see: J. Chem. Soc., Perkin 1, 1214 (1973); Org. Synth. Coll., 7, 356 (1990).

Cai, X.; Li, Y.; Yue, D.; Yi, Q.; Li, S.; Shi, D.; Gu, Z. Reversible PEGylation and Schiff-base linked imidazole modification of polylysine for high-performance gene delivery. J. Mater. Chem. B 2015, 3 (8), 1507-1517.

Wang, Q. M.; Gao, Z.; Liu, S.; Fan, B.; Kang, L.; Huang, W.; Jin, M. Hybrid polymeric micelles based on bioactive polypeptides as pH-responsive delivery systems against melanoma. Biomaterials 2014, 35 (25), 7008-7021.

Rischio GHS e dichiarazioni precauzionali

Dichiarazioni di rischio (UE): H314-H335-H227

Causes severe skin burns and eye damage. May cause respiratory irritation. Combustible liquid.

Dichiarazioni precauzionali: P210-P260-P261-P280-P303+P361+P353-P305+P351+P338-P301+P330+P331-P304+P340-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not breathe dust/fume/gas/mist/vapours/spray. Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Altri riferimenti

Merck
14,4778
Beilstein
3587158
Classe di rischio
8
Gruppo di imballaggio
II
Codice tariffe armonizzato
2811.19
TSCA
Yes
RTECS
MW3850000

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