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501-52-0 - 3-Phenylpropionic acid, 99% - Hydrocinnamic acid - A14908 - Alfa Aesar

A14908 3-Phenylpropionic acid, 99%

Codice CAS
501-52-0
Sinonimi
Hydrocinnamic acid

Dimensioni Prezzo ($) Quantità Disponibilità
100g 35,23
500g 126,40
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3-Phenylpropionic acid, 99%

MDL
MFCD00002771
EINECS
207-924-5

Proprietà chimiche

Formula
C6H5(CH2)2CO2H
Peso formula
150.18
Punto di fusione
47-50°
Punto di ebollizione
280°
Punto di infiammabilità
>110°(230°F)
Densità
1.071
Solubilità
Soluble in water

Applicazioni

Hydrocinnamic acid is inhibitor of carboxypeptidase. Hydrocinnamic acid was used in the synthesis of three medium-chain acyl-Coenzyme A?s i.e. 3-phenylpropionyl-CoA from mixed anhydrides of fatty acids.

Note

Store away from strong oxidizing agents. Keep container tightly closed. Store in cool, dry conditions in well sealed containers.

Letteratura

P. Moesta.; H. Grisebach. l-2-Aminooxy-3-phenylpropionic acid inhibits phytoalexin accumulation in soybean with concomitant loss of resistance against Phytophthora megasperma f. sp. glycinea . Physiological Plant Pathology. 1982, 21, (1), 65-70.

Olivier Ploux.; Manuel Caruso.; Gerard Chassaing.; Andree Marquet. A new modified amino acid. 2-Amino-3-mercapto-3-phenylpropionic acid (3-mercaptophenylalanine). Synthesis of derivatives, separation of stereoisomers, and assignment of absolute configuration. J. Org. Chem. 1988,, 53, (14), 3154-3158.

For the abnormal reaction with thionyl chloride leading to a benzo[b]thiophene derivative, see trans-Cinnamic acid, A13538.

Free radical oxidative cyclization with ɑß-unsaturated nitriles, ketones and esters gives tetrahydronaphthalene derivatives: Tetrahedron Lett., 36, 4307 (1995). For reaction scheme, see Acryl­onitrile, A13058.

Rischio GHS e dichiarazioni precauzionali

Dichiarazioni di rischio (UE): H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Dichiarazioni precauzionali: P261-P280-P305+P351+P338-P304+P340-P362-P312-P321-P405-P403+P233-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. Call a POISON CENTER or doctor/physician if you feel unwell. Specific treatment (see label). Store locked up. Store in a well-ventilated place. Keep container tightly closed. Dispose of contents/container in accordance with local/regional/national/international regulations.

Altri riferimenti

Merck
14,4784
Beilstein
907515
Codice tariffe armonizzato
2916.39
TSCA
Yes
RTECS
DA8600000

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