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13395-16-9 - Copper(II) 2,4-pentanedionate, 98% - Bis(acetylacetonato)copper(II) - Bis(2,4-pentanedionato)copper(II) - A14920 - Alfa Aesar

A14920 Copper(II) 2,4-pentanedionate, 98%

Codice CAS
13395-16-9
Sinonimi
Bis(acetylacetonato)copper(II)
Bis(2,4-pentanedionato)copper(II)

Dimensioni Prezzo ($) Quantità Disponibilità
25g 23,76
50g 34,35
100g 55,62
500g 193,20
1000g 338,87
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Copper(II) 2,4-pentanedionate, 98%

MDL
MFCD00000016
EINECS
236-477-9

Proprietà chimiche

Formula
C10H14CuO4
Peso formula
261.76
Punto di fusione
ca 286° dec.
Punto di ebollizione
160°/10mm
Solubilità
Insoluble in water.

Applicazioni

Copper(II) 2,4-pentanedionate is used as a catalyst for carbene transfer reactions, coupling reactions and Michael addition reactions. It is also used as a catalyst for the polymerization of olefins and transesterification reactions as well as a PVC stabilizer. Further, it is used as a curing agent for epoxy resins, acrylic adhesives, silicone rubbers. In addition to this, it is used as a lubricant additive and paint drier.

Note

Incompatible with strong oxidizing agents.

Letteratura

The most effective of a number of metal chelates studied in enabling the reduction of aromatic nitro-compounds by sodium borohydride: J. Chem. Soc., Perkin 1, 2409 (1979).

Promotes the coupling of organozinc reagents with allylic halides to give , δ-unsaturated esters: Tetrahedron Lett., 24, 2749 (1983).

Catalyst for the carbenoid reaction of diazoacetate esters with silyl enol ethers to give siloxycyclopropanes: Liebigs Ann. Chem., 512 (1984); Org. Synth. Coll., 9, 573 (1998).

In catalytic amounts promotes the selective O-benzylation of primary alcohols with benzyl chloride, in the presence of secondary alcohols or phenols: Tetrahedron Lett., 44, 8483 (2003). For a brief feature on uses of the reagent in synthesis, see: Synlett, 2859 (2005).

Jia, Y.; Su, J.; Chen, Z.; Tan, K.; Chen, Q.; Cao, Z.; Jiang, Y.; Xie, Z.; Zheng, L. Composition-tunable synthesis of Pt-Cu octahedral alloy nanocrystals from PtCu to PtCu3 via underpotential-deposition-like process and their electro-catalytic properties. RSC Adv. 2015, 5 (23), 18153-18158.

Staniuk, M.; Zindel, D.; van Beek, W.; Hirsch, O.; Kränzlin, N.; Niederberger, M.; Koziej, D. Matching the organic and inorganic counterparts during nucleation and growth of copper-based nanoparticles - in situ spectroscopic studies. CrystEngComm 2015, 17, 6962-6971.

Rischio GHS e dichiarazioni precauzionali

Dichiarazioni di rischio (UE): H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Dichiarazioni precauzionali: P261-P280-P305+P351+P338-P304+P340-P362-P312-P321-P405-P403+P233-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. Call a POISON CENTER or doctor/physician if you feel unwell. Specific treatment (see label). Store locked up. Store in a well-ventilated place. Keep container tightly closed. Dispose of contents/container in accordance with local/regional/national/international regulations.

Altri riferimenti

Beilstein
4157957
Codice tariffe armonizzato
2914.19
TSCA
Yes
RTECS
GL6520000

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