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107-18-6 - Allyl alcohol, 98+% - 2-Propen-1-ol - 3-Hydroxy-1-propene - A15026 - Alfa Aesar

A15026 Allyl alcohol, 98+%

Codice CAS
107-18-6
Sinonimi
2-Propen-1-ol
3-Hydroxy-1-propene

Dimensioni Prezzo ($) Quantità Disponibilità
100ml 15,00
500ml 28,20
2500ml 102,00
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Allyl alcohol, 98+%

MDL
MFCD00002920
EINECS
203-470-7

Proprietà chimiche

Formula
C3H6O
Peso formula
58.08
Punto di fusione
-129°
Punto di ebollizione
95-97°
Punto di infiammabilità
22°(71°F)
Densità
0.852
Indice di rifrazione
1.4130
Solubilità
Miscible with water.

Applicazioni

Allyl alcohol is widely used as a precursor to many specialized compounds such as allyl glycidyl ether, allyl diglycidyl carbonate, allyl methacrylate, flame-resistant materials, drying oils and plasticizers. It is used as a raw material for the synthesis of glycerol, glycidyl ethers, esters and amines. It is involved in the synthesis of a variety of polymerizable esters such as diallyl phthalate.

Note

Incompatible with strong oxidizing agents, acids, oleum and alkali metals. Polymerizes during prolonged storage.

Letteratura

Carboxylic acids can be protected as allyl esters, by reaction of allyl alcohol with an activated carboxyl group. They are readily cleaved in the presence of Pd catalysts: J. Org. Chem., 47, 587 (1982); Angew. Chem. Int. Ed., 23, 71 (1984); J. Chem. Soc., Chem. Commun., 1216 (1990).

Harvey, L.; Sánchez, G.; Kennedy, E. M.; Stockenhuber, M. Enhancing allyl alcohol selectivity in the catalytic conversion of glycerol; influence of product distribution on the subsequent epoxidation step. Asia-Pac. J. Chem. 2015, 10 (4), 598-606.

Fukuda, K.; Tojino, M.; Goto, K.; Dohi, H.; Nishida, Y.; Mizuno, M. A recyclable heavy fluorous tag carrying an allyl alcohol pendant group: design and evaluation toward applications in synthetic carbohydrate chemistry. Carbohydr. Res. 2015, 407, 122-130.

Rischio GHS e dichiarazioni precauzionali

Dichiarazioni di rischio (UE): H225-H301-H311-H331-H315-H319-H335

Highly flammable liquid and vapour. Toxic if swallowed. Toxic in contact with skin. Toxic if inhaled. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Dichiarazioni precauzionali: P210-P301+P310a-P303+P361+P353-P305+P351+P338-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. IF SWALLOWED: Immediately call a POISON CENTER/doctor IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Altri riferimenti

Merck
14,286
Beilstein
605307
Classe di rischio
6.1
Gruppo di imballaggio
I
Codice tariffe armonizzato
2905.29
TSCA
Yes
RTECS
BA5075000

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