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328-74-5 - 3,5-Bis(trifluoromethyl)aniline, 98% - A15289 - Alfa Aesar

A15289 3,5-Bis(trifluoromethyl)aniline, 98%

Codice CAS
328-74-5
Sinonimi

Dimensioni Prezzo ($) Quantità Disponibilità
10g 38,76
50g 129,60
250g 448,00
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3,5-Bis(trifluoromethyl)aniline, 98%

MDL
MFCD00000394
EINECS
206-335-0

Proprietà chimiche

Formula
C8H5F6N
Peso formula
229.13
Punto di ebollizione
75-78°/10mm
Punto di infiammabilità
83°(181°F)
Densità
1.473
Indice di rifrazione
1.4340
Solubilità
Not miscible in water.

Applicazioni

3,5-Bis(trifluoromethyl)aniline was used in the synthesis of N-[2-hydroxy-1-naphthylidene]-3, 5-bis(trifluoromethyl)aniline, Schiff?s base and 5,7-bis(trifluoromethyl)aniline. It was also used in the synthesis of N-1-phenylethyl-3,5-bis(trifluoromethyl)aniline via titanium-catalyzed hydroamination reaction and N,N?-bis[3,5-bis(tri-fluoromethyl)phenyl]thiourea, organocatalyst.

Note

Stable under recommended storage conditions. Incompatible with oxidizing agents.

Letteratura

Ludwig T.Kaspar; Benjamin Fingerhut; Lutz Ackermann. Titanium-catalyzed intermolecular hydroamination of vinylarene. Angewandte Chemie (International Edition). 2005, 44,(37), 5972-5974.

 

Yunoh Jung; Kang-Jun Baeg; Dong-Yu Kim; Takao Someya; Soo Young Park. A thermally resistant and air-stable n-type organic semiconductor: Naphthalene diimide of 3,5-bis-trifluoromethyl aniline. Synthetic Metals. 2009, 159,(19-20), 2117-2121.

Rischio GHS e dichiarazioni precauzionali

Dichiarazioni di rischio (UE): H331-H302-H312-H315-H319-H373-H227

Toxic if inhaled. Harmful if swallowed. Harmful in contact with skin. Causes skin irritation. Causes serious eye irritation. May cause damage to organs through prolonged or repeated exposure. Combustible liquid.

Dichiarazioni precauzionali: P210-P260-P261-P280-P305+P351+P338-P304+P340-P311-P362-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not breathe dust/fume/gas/mist/vapours/spray. Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/physician. Take off contaminated clothing and wash before reuse. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Altri riferimenti

Beilstein
654318
Classe di rischio
6.1
Gruppo di imballaggio
III
Codice tariffe armonizzato
2921.49
TSCA
Yes
RTECS
ZE9800000

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