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7727-21-1 - Potassium peroxydisulfate, 97% - Peroxydisulfuric acid dipotassium salt - Potassium persulfate - A15310 - Alfa Aesar

A15310 Potassium peroxydisulfate, 97%

Codice CAS
7727-21-1
Sinonimi
Peroxydisulfuric acid dipotassium salt
Potassium persulfate

Dimensioni Prezzo ($) Quantità Disponibilità
500g 46,10
2500g 182,00
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Potassium peroxydisulfate, 97%

MDL
MFCD00011386
EINECS
231-781-8

Proprietà chimiche

Formula
K2O8S2
Peso formula
270.33
Punto di fusione
100° dec.
Densità
2.477
Solubilità
Soluble in water. Insoluble in alcohol.

Applicazioni

Potassium peroxydisulfate is used as an oxidizing agent in organic synthesis. It is involved in the Elbs persulfate oxidation of phenols and the Boyland-Sims oxidation of anilines. In solution, it gives radicals and is used to initiate polymerization reactions to prepare styrene-butadiene rubber and polytetrafluoroethylene. It is used as a bleaching agent in various hair bleaches, as an ion exchange agent, a plating agent and a surface treating agent.

Note

Moisture sensitive. Incompatible with organic materials, strong reducing agents, powdered metals, strong bases, alcohols, phosphorous, anhydrides, halogens and acids.

Letteratura

Useful oxidant: J. Org. Chem., 25, 1901 (1960); examples:

Conversion of phenols to para-diphenols in alkaline solution (Elbs oxidation), and of arylamines to aminophenols (Boyland-Sims oxidation); review: Org. React., 35, 421 (1988). Phase-transfer conversion of acids to peracids in the presence of BTEAC or PEG: Synth. Commun., 18, 2123 (1988). In the presence of Na2HPO4 in acetone - dichloromethane, arylamines give nitro arenes: Tetrahedron Lett., 29, 4501 (1988). In the presence of Ni(II) salts, primary alkylamines can undergo dehydrogenation to nitriles: Bull. Chem. Soc. Jpn., 63, 301 (1990).

See also Ammonium peroxydisulfate, A10533, and Sodium peroxydisulfate, 54100.

Patil, V. V.; Shankarling, G. S. Steric-Hindrance-Induced Regio-and Chemoselective Oxidation of Aromatic Amines. J. Org. Chem. 2015, 80 (16), 7876-7883.

Anirudhan, T. S.; Suchithra, P. S.; Senan, P.; Tharun, A. R. Kinetic and equilibrium profiles of adsorptive recovery of thorium(IV) from aqueous solutions using poly (methacrylic acid) grafted cellulose/bentonite superabsorbent composite. Ind. Eng. Chem. Res. 2012, 51 (13), 4825-4836.

Rischio GHS e dichiarazioni precauzionali

Dichiarazioni di rischio (UE): H334-H315-H319-H317-H272-H302-H335

May cause allergy or asthma symptoms or breathing difficulties if inhaled. Causes skin irritation. Causes serious eye irritation. May cause an allergic skin reaction. May intensify fire; oxidizer. Harmful if swallowed. May cause respiratory irritation.

Dichiarazioni precauzionali: P221-P210-P285-P220-P261-P280-P305+P351+P338-P304+P340-P405-P501a

Take any precaution to avoid mixing with combustibles. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. In case of inadequate ventilation wear respiratory protection. Keep/Store away from clothing/combustible materials. Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Altri riferimenti

Merck
14,7656
Classe di rischio
5.1
Gruppo di imballaggio
III
Codice tariffe armonizzato
2833.40
TSCA
Yes
RTECS
SE0400000

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