Informativa e consenso per l'uso dei cookie

Accetto Il nostro sito salva piccoli pezzi di informazioni (cookie) sul dispositivo, al fine di fornire contenuti migliori e per scopi statistici. È possibile disattivare l'utilizzo di cookies modificando le impostazioni del tuo browser. Continuando la navigazione si acconsente all'utilizzo dei cookie.

366-18-7 - 2,2'-Bipyridine, 99+% - 2,2'-Bipyridyl - 2,2'-Dipyridyl - A15782 - Alfa Aesar

A15782 2,2'-Bipyridine, 99+%

Codice CAS
366-18-7
Sinonimi
2,2'-Bipyridyl
2,2'-Dipyridyl

Dimensioni Prezzo ($) Quantità Disponibilità
25g 51,91
100g 144,90
500g 484,51
Aggiungi al carrello Aggiungi al preventivo generale Visualizza articolo

2,2'-Bipyridine, 99+%

MDL
MFCD00006212
EINECS
206-674-4

Proprietà chimiche

Formula
C10H8N2
Peso formula
156.19
Punto di fusione
70°
Punto di ebollizione
272-273°
Punto di infiammabilità
121°(249°F)
Solubilità
Soluble in organic solvents and slightly soluble in water.

Applicazioni

Reagent for iron determinations.2,2'-bipyridine acts as a bidentate chelating ligand which form complexes with transition metal ions and shows antifungal, antibacterial and antiviral activity. It is used for the colorimetric determination of iron as well as oxidation reduction indicators to confirm the presence of ferrous ion in soils. It forms complexes with ruthenium and platinum, exhibit intense luminescence, which may have practical applications. Copper(I) bipyridine complexes involved in the oxidation of alcohols under aerobic conditions.

Note

Keep container tightly closed in a dry and well-ventilated place. Keep away from sources of ignition.

Letteratura

Reagent for iron. Chelating ligand.

For use as an alternative to phosphines in Heck type reactions, see: Synlett, 871 (1992).

Complex with Chromium(VI)­ oxide, 12522, has been used in a mild selective oxidation of alcohols to aldehydes and ketones: Acta Chem. Scand., 25, 1125 (1971).

/n

Valvekens, P.; Bloch, E. D.; Long, J. R.; Ameloot, R.; De Vos, D. E. Counteranion effects on the catalytic activity of copper salts immobilized on the 2,2'-bipyridine-functionalized metal-organic framework MOF-253. Catal. Today 2015, 246, 55-59.

Kageshima, Y.; Kumagai, H.; Minegishi, T.; Kubota, J.; Domen, K. A Photoelectrochemical Solar Cell Consisting of a Cadmium Sulfide Photoanode and a Ruthenium-2,2'-Bipyridine Redox Shuttle in a Non-aqueous Electrolyte. Angew. Chem. 2015, 127 (27), 7988-7992.

Rischio GHS e dichiarazioni precauzionali

Dichiarazioni di rischio (UE): H301-H312

Toxic if swallowed. Harmful in contact with skin.

Dichiarazioni precauzionali: P280-P264-P270-P301+P310-P312-P363-P321-P322-P405-P501a

Wear protective gloves/protective clothing/eye protection/face protection. Wash thoroughly after handling. Do not eat, drink or smoke when using this product. IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. Call a POISON CENTER or doctor/physician if you feel unwell. Wash contaminated clothing before reuse. Specific treatment (see label). Specific measures (see label). Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Altri riferimenti

Merck
14,3347
Beilstein
113089
Classe di rischio
6.1
Gruppo di imballaggio
III
Codice tariffe armonizzato
2933.39
TSCA
Yes
RTECS
DW1750000

Raccomandato

  • A10249

    Tetra-n-butylammonium bromide, 98+%
  • A11391

    Pyridine-2-carboxaldehyde, 99%
  • A11591

    Ethylene glycol, 99%
  • A13163

    1,10-Phenanthroline, 99%, may contain up to 1.5% water
  • 11043

    Ruthenium(III) chloride hydrate, 99.9% (PGM basis), Ru 38% min

Visualizzati di recente

Prodotti chimici

Scienze della vita

Metalli e materiali

Catalizzatori

Apparecchiature di analisi e di laboratorio