Autorizzo l’utilizzo di cookies.

Accetto Utilizziamo cookies per migliorare il nostro servizio e realizzare statistiche. Questa funzione puó essere disattivata cambiando la configurazione del browser. Continuando a navigare senza modificare questi parametri, consideriamo che l’uso di cookies sia accettato

7440-16-6 - Rhodium, 5% on carbon, dry - A15965 - Alfa Aesar

A15965 Rhodium, 5% on carbon, dry

Codice CAS
7440-16-6
Sinonimi

Dimensioni Prezzo ($) Quantità Disponibilità
1g 55,10
5g 202,00
25g 798,00
Aggiungi al carrello Aggiungi al preventivo generale Visualizza articolo

Rhodium, 5% on carbon, dry

MDL
MFCD00011201
EINECS
231-125-0

Proprietà chimiche

Formula
Rh
Solubilità
Insoluble in water.

Applicazioni

Rhodium, 5% on carbon is a useful reagent for the conversation of nitriles to primary amines and the hydrogenation of aromatic rings, pyridines, aldehydes and sugars. It is also used for the reduction of oximes to amines and for the reduction of nitrobenzene to phenylhydroxylamine using hydrazine hydrate as the hydrogen source.

Note

Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Incompatible with strong oxidizing agents, halogens, chlorine trifluoride and oxygen difluoride.

Letteratura

Joseph J. Mrowca.; Thomas J. Katz. Catalysis of a Cycloaddition Reaction by Rhodium on Carbon. J. Am. Chem. Soc. 1966, 88 (17), 4012-4015 .

Morris Freifelder.; Ralph M. Robinson.; George R. Stone. Hydrogenation of Substituted Pyridines with Rhodium on Carbon Catalyst. J. Org. Chem. 1962, 27 (1), 284-286.

Rhodium catalysts are especially useful for the hydrogenation of aromatic rings under mild conditions. For details for the hydrogenation of 4-aminobenzoic acid to its hexahydro derivative under modest pressure, see: Org. Synth. Coll., 5, 670 (1973).

Rhodium catalysts have also been used for the reduction of oximes to amines.

For a monograph on catalytic hydrogenation, see: P. N. Rylander, Hydrogenation Methods, Academic Press, N.Y. (1985).

For the reduction of nitrobenzene to phenylhydroxylamine using hydrazine hydrate as the hydrogen source, see: Org. Synth. Coll., 8, 16 (1993).

Rischio GHS e dichiarazioni precauzionali

Dichiarazioni di rischio (UE): H228-H315-H319-H335

Flammable solid. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Dichiarazioni precauzionali: P210-P261-P280a-P305+P351+P338-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves and eye/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Altri riferimenti

Merck
14,8186
Classe di rischio
4.1
Gruppo di imballaggio
III
Codice tariffe armonizzato
3815.12
TSCA
Yes
RTECS
VI9069000

Raccomandato

  • A10752

    Agar powder
  • 11770

    Rhodium, 5% on alumina powder, reduced
  • 38330

    Iridium, 1% on activated carbon powder, reduced, nominally 50% water wet
  • 44222

    Platinum, 5% on alumina powder, reduced

Visualizzati di recente

Prodotti chimici

Scienze della vita

Metalli e materiali

Catalizzatori

Apparecchiature di analisi e di laboratorio