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831-91-4 - Benzyl phenyl sulfide, 98% - A16171 - Alfa Aesar

A16171 Benzyl phenyl sulfide, 98%

Codice CAS
831-91-4
Sinonimi

Dimensioni Prezzo ($) Quantità Disponibilità
25g 44,50
100g 126,00
500g 510,00
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Benzyl phenyl sulfide, 98%

MDL
MFCD00003066
EINECS
212-612-7

Proprietà chimiche

Formula
C6H5CH2SC6H5
Peso formula
200.30
Punto di fusione
39-42°
Punto di ebollizione
167-168°/10mm
Punto di infiammabilità
>110°(230°F)
Solubilità
Insoluble in water.

Applicazioni

Benzyl phenyl sulfide is used in dyestuff intermediate, flavor & fragrance intermediate and organic intermediate.

Note

Stable under recommended storage conditions. Incompatible with oxidizing agents.

Letteratura

Yong Hyeon Yim; Kwan Kim; Myung Soo Kim. Adsorption and decomposition of benzyl phenyl sulfide on silver surface investigated by Raman spectroscopy. J. Phys. Chem. 1990, 94, (6),2552-2556

 

Inhyung Lee; Sang Woo Han; Chang Hwan Kim; Taeg Gyum Kim; Sang Woo Joo; Du-Jeon Jang; Kwan Kim. Surface-induced photoreaction of benzyl phenyl sulfide monolayers on silver and its application to preparing patterned binary monolayers. Langmuir. 2000, 16, (26),9963-9967

Has been used in a sequence for the introduction of an ortho-substituent into aromatic amines by base-induced rearrangement of an amino sulfonium salt: J. Am. Chem. Soc., 100, 7600 (1978):

Lithiation of phenylthioethers, (t-BuLi/HMPA) leads exclusively to the ɑ-lithio derivatives, which react with electrophiles such as alkyl halides and carbonyl compounds: Tetrahedron Lett., 1961 (1977).

Rischio GHS e dichiarazioni precauzionali

Dichiarazioni precauzionali: P260u-P201-P280-P303+P361+P353-P305+P351+P338-P301+P330+P331-P304+P340-P310a-P405-P501a

Obtain special instructions before use. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Altri riferimenti

Beilstein
1909409
Codice tariffe armonizzato
2930.90
TSCA
No

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