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108-05-4 - Vinyl acetate, 99%, stab. with 8-12ppm hydroquinone - Acetic acid vinyl ester - A16247 - Alfa Aesar

A16247 Vinyl acetate, 99%, stab. with 8-12ppm hydroquinone

Codice CAS
108-05-4
Sinonimi
Acetic acid vinyl ester

Dimensioni Prezzo ($) Quantità Disponibilità
100ml 18,64
500ml 22,05
2500ml 47,28
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Vinyl acetate, 99%, stab. with 8-12ppm hydroquinone

MDL
MFCD00008713
EINECS
203-545-4

Proprietà chimiche

Formula
C4H6O2
Peso formula
86.09
Punto di fusione
-100°
Punto di ebollizione
72-73°
Punto di infiammabilità
-8°(18°F)
Densità
0.932
Indice di rifrazione
1.3960
Solubilità
Slightly miscible with water.

Applicazioni

Vinyl acetate is used in the preparation of polyvinyl acetate emulsions and polyvinyl alcohol. It acts as a precursor to polyvinyl acetate. It serves as an ingredient in furniture-glue. It is also used to prepare copolymers with other monomers such as ethylene, acrylic acid. Further, it is used to make adhesives, paints and plastics.

Note

Light sensitive. Incompatible with acids, bases, oxidizing agents, peroxides, chlorosulfonic acid, ethylene imine, hydrochloric acid, oleum, nitric acid, sulfuric acid and 2-aminoethanol.

Letteratura

For example of mercuric acetate-catalyzed transesterification to long-chain vinyl esters, see: Org. Synth. Coll., 4, 977 (1963).

For thermal [2+2] cycloaddition with chlorotrifluoroethylene, see: Org. Synth. Coll., 5, 235 (1973); and with chlorosulfonyl isocyanate to give a ß-lactam: Org. Synth. Coll., 8, 3 (1993).

Dong, X.; Guan, X.; Jiang, Y.; Ma, J.; Zhang, M. Extension of the TraPPE-UA force field to the simulation of vapor-liquid phase equilibria of vinyl acetate system. J. Mol. Liq. 2015, 209, 520-525.

Belbekhouche, S.; Picton, L.; Le Cerf, D.; Hamaide, T. Pullulan-Based Polymer Surfactants for Vinyl Acetate Miniemulsion Polymerization: Kinetics and Colloidal Stability Investigations. Macromol. Chem. Phys. 2015, 216 (18), 1879-1887.

Rischio GHS e dichiarazioni precauzionali

Dichiarazioni di rischio (UE): H225-H351-H332-H335-H303-H313

Highly flammable liquid and vapour. Suspected of causing cancer. Harmful if inhaled. May cause respiratory irritation. May be harmful if swallowed. May be harmful in contact with skin.

Dichiarazioni precauzionali: P210-P201-P261-P280-P281-P240-P303+P361+P353-P304+P340-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Obtain special instructions before use. Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. Use personal protective equipment as required. Ground/bond container and receiving equipment. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Altri riferimenti

Merck
14,9992
Beilstein
1209327
Classe di rischio
3
Gruppo di imballaggio
II
Codice tariffe armonizzato
2915.32
TSCA
Yes
RTECS
AK0875000

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