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1148-79-4 - 2,2':6',2''-Terpyridine, 97% - 2,6-Bis(2-pyridyl)pyridine - A17750 - Alfa Aesar

A17750 2,2':6',2''-Terpyridine, 97%

Codice CAS
1148-79-4
Sinonimi
2,6-Bis(2-pyridyl)pyridine

Dimensioni Prezzo ($) Quantità Disponibilità
0.25g 44,80
1g 115,00
5g 388,00
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2,2':6',2''-Terpyridine, 97%

MDL
MFCD00006213
EINECS
214-559-5

Proprietà chimiche

Formula
C15H11N3
Peso formula
233.28
Punto di fusione
89-92°
Solubilità
Soluble in most organic solvents.

Applicazioni

2,2';6',2"-terpyridine is widely utilized in the field of supramolecular chemistry, which is used to manufacture the racks, ladders and grids, helicates, catenanes and dendrimers. It plays an important role as a ligand in coordination chemistry. Its complexes are employed in the oxidation of alcohols, the carbonylation of aromatic compounds and as oxygen-binding molecules. Functionalized terpyridine ligands were used in semiconductors and solar panels. It forms chealate complexes with europium(III) and terbium(III), which is used in protein labelling.

Note

Keep container tightly closed in a dry and well-ventilated place. Incompatible with strong oxidizing agents.

Letteratura

Schönle, J.; Constable, E. C.; Housecroft, C. E.; Prescimone, A.; Zampese, J. E. Homoleptic and heteroleptic complexes of chromium(III) containing 4'-diphenylamino-2,2':6',2?-terpyridine ligands. Polyhedron 2015, 89 182-188.

Harper, B. W. J.; Aldrich-Wright, J. R. The synthesis, characterisation and cytotoxicity of bisintercalating (2,2':6',2''-terpyridine)platinum(II) complexes. Dalton Trans. 2015, 44 (1), 87-96.

Rischio GHS e dichiarazioni precauzionali

Dichiarazioni di rischio (UE): H300-H310-H315-H319-H335

Fatal if swallowed. Fatal in contact with skin. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Dichiarazioni precauzionali: P261-P262-P280-P301+P310-P305+P351+P338-P361-P302+P350-P304+P340-P405-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Do not get in eyes, on skin, or on clothing. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Remove/Take off immediately all contaminated clothing. IF ON SKIN: Gently wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Altri riferimenti

Classe di rischio
6.1
Gruppo di imballaggio
I
Codice tariffe armonizzato
2933.39
TSCA
Yes

Raccomandato

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  • 11495

    Ammonium hexafluorophosphate, 99.5%
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