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22445-41-6 - 5-Iodo-m-xylene, 98% - 1,3-Dimethyl-5-iodobenzene - 1-Iodo-3,5-dimethylbenzene - A18413 - Alfa Aesar

A18413 5-Iodo-m-xylene, 98%

Codice CAS
22445-41-6
Sinonimi
1,3-Dimethyl-5-iodobenzene
1-Iodo-3,5-dimethylbenzene

Dimensioni Prezzo ($) Quantità Disponibilità
10g 42,85
50g 149,35
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5-Iodo-m-xylene, 98%

MDL
MFCD00060659
EINECS
000-000-0

Proprietà chimiche

Formula
C8H9I
Peso formula
232.07
Punto di ebollizione
229°
Punto di infiammabilità
>110°(230°F)
Densità
1.610
Indice di rifrazione
1.5950
Sensibilità
Light Sensitive
Solubilità
Sparingly soluble (0.014 g/L) (25°C), Calc.

Applicazioni

1-Iodo-3,5-dimethylbenzene (5-iodo-m-xylene) is suitable for use in the synthesis of N-(3,5-xylyl)-N-ethyl aniline, an aryl amine, It is also used in the following studies; α-Arylation of ketones, Copper-catalyzed N-arylation of imidazoles, Cyanation of 5-iodo-m-xylene to form 3,5-dimethylbenzonitrile, synthesis of 1,3-Dimethyl-5-phenoxybenzene by nano-CuFe2O4 catalyzed C-O cross-coupling with phenol, CuBr-catalyzed amination of 1-iodo-3,5-dimethylbenzene to form N-Allyl-3,5-dimethylbenzenamine, copper-catalyzed C-S bond-formation between 5-iodo-m-xylene and thiophenol. It is also employed as a starting material in the synthesis of biphenyl-3,3’,5,5’-tetracarboxylic acid, radical bromination of 5-iodo-m-xylene by N-bromosuccinimide to form 1,3-bis(bromomethyl)-5-iodobenzene.

Note

Light Sensitive. Store away from oxidizing agents and light. Keep the container tightly closed and place it in a cool, dry and well ventilated condition.

Letteratura

M H Ali.; S L Buchwald. An improved method for the palladium-catalyzed amination of aryl iodides. Org Chem.2001,66(8), 2560-2565.

Anouk S Lubbe, et. al. Control of rotor function in light-driven molecular motors.J. Org Chem.2011,76(21), 8599-8610.

Rischio GHS e dichiarazioni precauzionali

Dichiarazioni di rischio (UE): H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Dichiarazioni precauzionali: P261-P280-P305+P351+P338-P304+P340-P362-P312-P321-P405-P403+P233-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. Call a POISON CENTER or doctor/physician if you feel unwell. Specific treatment (see label). Store locked up. Store in a well-ventilated place. Keep container tightly closed. Dispose of contents/container in accordance with local/regional/national/international regulations.

Altri riferimenti

Beilstein
2039353
Codice tariffe armonizzato
2903.99
TSCA
No

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