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1477-50-5 - Indole-2-carboxylic acid, 98+% - A18690 - Alfa Aesar

A18690 Indole-2-carboxylic acid, 98+%

Codice CAS
1477-50-5
Sinonimi

Dimensioni Prezzo ($) Quantità Disponibilità
10g 57,06
50g 169,59
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Indole-2-carboxylic acid, 98+%

MDL
MFCD00005611
EINECS
216-030-4

Proprietà chimiche

Formula
C9H7NO2
Peso formula
161.16
Punto di fusione
ca 205° dec.
Solubilità
Soluble in clear yellow solution 5% in ethanol, dimethyl sulfoxide and methanol.

Applicazioni

Reactant for total synthesis of (±)-dibromophakellin and analogs, synthesis of the pyrrolizidine alkaloid (±)-trachelanthamidine, stereo selective preparation of renieramycin G analogs, preparation of spirooxoindolepyrrolidines via reduction of indole-2-carboxylic acid followed by oxidation, condensation, reduction, amidation and Kharasch radical cyclization, Pd-catalyzed cyclization and N,N?-(pentane)diylbis[indolecarboxamide] and N,N?-[phenylenebis(methylene)]bis[indolecarboxamide] derivatives.

Note

Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from oxidizing agent.

Letteratura

Nicole M Hewlett; and Jetze J Tepe.Total synthesis of the natural product (±)-dibromophakellin and analogues. Organic Letters, 2011, 13 (17), 4550-4553.

Stefano Nicolai et. al. A palladium-catalyzed aminoalkynylation strategy towards bicyclic heterocycles: synthesis of (±)-trachelanthamidine. Angewandte Chemie. International edition in English, 2011, 50(20), 4680-4683.

Rischio GHS e dichiarazioni precauzionali

Dichiarazioni di rischio (UE): H301-H311-H315-H319-H335

Toxic if swallowed. Toxic in contact with skin. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Dichiarazioni precauzionali: P261-P280-P301+P310-P305+P351+P338-P361-P304+P340-P362-P312-P405-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Remove/Take off immediately all contaminated clothing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. Call a POISON CENTER or doctor/physician if you feel unwell. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Altri riferimenti

Beilstein
124132
Codice tariffe armonizzato
2933.99
TSCA
No
RTECS
NK7882812

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