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1477-50-5 - Indole-2-carboxylic acid, 98+% - A18690 - Alfa Aesar

A18690 Indole-2-carboxylic acid, 98+%

Codice CAS
1477-50-5
Sinonimi

Dimensioni Prezzo ($) Quantità Disponibilità
10g 56,80
50g 184,00
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Indole-2-carboxylic acid, 98+%

MDL
MFCD00005611
EINECS
216-030-4

Proprietà chimiche

Formula
C9H7NO2
Peso formula
161.16
Punto di fusione
ca 205° dec.
Solubilità
Soluble in clear yellow solution 5% in ethanol, dimethyl sulfoxide and methanol.

Applicazioni

Reactant for total synthesis of (±)-dibromophakellin and analogs, synthesis of the pyrrolizidine alkaloid (±)-trachelanthamidine, stereo selective preparation of renieramycin G analogs, preparation of spirooxoindolepyrrolidines via reduction of indole-2-carboxylic acid followed by oxidation, condensation, reduction, amidation and Kharasch radical cyclization, Pd-catalyzed cyclization and N,N?-(pentane)diylbis[indolecarboxamide] and N,N?-[phenylenebis(methylene)]bis[indolecarboxamide] derivatives.

Note

Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from oxidizing agent.

Letteratura

Nicole M Hewlett; and Jetze J Tepe.Total synthesis of the natural product (±)-dibromophakellin and analogues. Organic Letters, 2011, 13 (17), 4550-4553.

Stefano Nicolai et. al. A palladium-catalyzed aminoalkynylation strategy towards bicyclic heterocycles: synthesis of (±)-trachelanthamidine. Angewandte Chemie. International edition in English, 2011, 50(20), 4680-4683.

Rischio GHS e dichiarazioni precauzionali

Dichiarazioni di rischio (UE): H301-H311-H315-H319-H335

Toxic if swallowed. Toxic in contact with skin. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Dichiarazioni precauzionali: P260u-P201-P280h-P303+P361+P353-P305+P351+P338-P301+P330+P331-P304+P340-P310a-P405-P501a

Obtain special instructions before use. Wear protective gloves/clothing. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Altri riferimenti

Beilstein
124132
Codice tariffe armonizzato
2933.99
TSCA
No
RTECS
NK7882812

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